Different assembled nano-MnO 2 fiber supercapacitors applied for smart wearable clothing

Abstract

With rapid development in the smart wearable field, new-style flexible energy storage devices are necessary to satisfy the demands of flexible smart clothing. Thereinto, fiber supercapacitors present promising application prospects. This work puts forward a facile and reliable strategy to fabricate coaxial fiber electrodes via binary wet spinning, and further assembles them into parallel or twisted nano-MnO₂ fiber supercapacitors. In the obtained fiber electrode, a carboxymethylcellulose layer onto nano-MnO₂ not only allows the requisite ion exchange between the electrochemical active materials and gel electrolyte, but also plays the role of separator to protect the two fiber electrodes effectively from contacting a short circuit, greatly ensuring the electrochemical stability of the nano-MnO₂ fiber supercapacitors. The parallel nano-MnO₂ fiber supercapacitor reaches a maximum C_L of 19.7 μF/cm, E_L of 0.0027 μWh/cm and P_L of 1.49 μW/cm; the twisted MnO₂ fiber supercapacitor achieves maximum C_L, E_L and P_L of 49 μF/cm, 0.0053 μWh/cm and 1.0 μW/cm, respectively. Besides, the outstanding softness and tensile properties of the obtained nano-MnO₂ fiber supercapacitors also guarantee stable electrochemical performance under bending, knotting or other large-distortion situations, which is beneficial to develop a new generation of metal oxide fiber supercapacitors for smart wearable clothing.

Keywords

Fiber supercapacitors parallel and twisted smart wearable clothing

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References

Chen

Fan

Wang

et al. A nano-micro structure engendered abrasion resistant, superhydrophobic, wearable triboelectric yarn for self-powered sensing. Nano Energ 2022; 103: 107769.

Fan

Zhang

Sun

et al. Durable antibacterial and temperature regulated core-spun yarns for textile health and comfort applications. Chem Eng J 2023; 455: 140917.

Luo

Miao

Wang

et al. Laser-induced janus graphene/poly (p-phenylene benzobisoxazole) fabrics with intrinsic flame retardancy as flexible sensors and breathable electrodes for fire-fighting field. Nano Res. 2023. DOI: 10.1007/s12274-023-5536-y

Fan

Zhang

Liu

et al. An ultra-thin piezoelectric nanogenerator with breathable, superhydrophobic, and antibacterial properties for human motion monitoring. Nano Res. 2023. DOI: 10.1007/s12274-023-5413-8

Zhao

Ying

Wang

et al. Covalent organic framework film protected zinc anode for highly stable rechargeable aqueous zinc-ion batteries. Energ Stor Mater 2022; 48: 82–89.

Wang

Zhao

Chen

et al. Molybdenum sulfide selenide ultrathin nanosheets anchored on carbon tubes for rapid-charging sodium/potassium-ion batteries. J Colloid Interface Sci 2022; 628: 1041–1048.

Khudiyev

Lee

Cox

et al. 100 m long thermally drawn supercapacitor fibers with applications to 3D printing and textiles. Adv Mater 2020; 32: 2004971.

Liang

Huang

et al. An overview of fiber-shaped batteries with a focus on multifunctionality, scalability, and technical difficulties. Adv Mater 2020; 32: 1902151.

Chen

Jiang

Huang

et al. Recent advances in fiber supercapacitors: materials, device configurations, and applications. Adv Mater 2020; 32: 1901806.

10.

Liu

Wang

et al. Constructing optimized wire electrodes for fiber supercapacitors. Nano Energ 2014; 10: 99–107.

11.

Saravanakumar

Jayaseelan

Seo

et al. NiCo₂S₄ nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications. Nanoscale 2017; 9: 18819–18834.

12.

Zhang

Tian

Song

et al. Study on preparation and performance of flexible all-solid-state supercapacitor based on nitrogen-doped RGO/CNT/MnO₂ composite fibers. J Alloys Compd 2021; 859: 157816.

13.

Qin

Peng

Hao

et al. Flexible and wearable all-solid-state supercapacitors with ultrahigh energy density based on a carbon fiber fabric electrode. Adv Energy Mater 2017; 7: 1700409.

14.

Liu

Zhu

et al. Nanocarbon-based materials for flexible all-solid-state supercapacitors. Adv Mater 2018; 30: 1705489.

15.

Lou

et al. Meters-long flexible CoNiO₂-nanowires@carbon-fibers based wire-supercapacitors for wearable electronics. Adv Mater Technol 2016; 1: 1600142.

16.

Cai

Ren

et al. Flexible, weavable and efficient microsupercapacitor wires based on polyaniline composite fibers incorporated with aligned carbon nanotubes. J Mater Chem A 2013; 1: 258–261.

17.

Cheng

Zhang

Ren

et al. The design of hierarchical ternary hybrid for fiber-shaped asymmetric supercapacitor with high volumetric energy density. J Phys Chem C 2016; 120: 9685–9691.

18.

Liu

Narayanasamy

Yang

et al. High-performance coaxial wire-shaped supercapacitors using ionogel electrolyte toward sustainable energy system. J Mater Res 2019; 34: 3030–3039.

19.

Zhang

Wang

Fan

et al. Doped CNC-Na₂CO₃ reinforcing alginate bio-based fiber as fire-safety composite applied in the household textile. Compos Commun 2023; 37: 101435.

20.

Yang

Jia

Niu

et al. Wet-spun PVDF nanofiber separator for direct fabrication of coaxial fibershaped supercapacitors. Chem Eng J 2020; 400: 125835.

21.

Zhang

Wang

Zhou

et al. Fabrication of aramid nanofiber-wrapped graphene fibers by coaxial spinning. Carbon 2020; 165: 340–348.

22.

Yang

Zhao

Niu

et al. Direct spinning of high-performance graphene fiber supercapacitor with a three-ply core-sheath structure. Carbon 2018; 132: 241–248.

23.

Liao

Wang

Hong

et al. Industrial scale production of fibre batteries by a solution-extrusion method. Nat Nanotechnol 2022; 17: 372.

24.

Fan

Zhang

et al. Superior unidirectional water transport and mechanically stable 3D orthogonal woven fabric for human body moisture and thermal management. Small 2022; 18: 2107150.

25.

Pang

and Zhu

Multifunctional amorphous Co phosphosulfide-coated Fe-Co carbonate hydroxide for highly efficient overall water splitting. J Electron Mater 2023; 52: 1808–1818.

26.

Wang

Yang

Chen

et al. Reliable coaxial wet spinning strategy to fabricate flexible MnO₂-based fiber supercapacitors. J Alloys Compd 2023; 935: 168110.

27.

Cai

Huang

Chen

et al. Wet-spinning of ternary synergistic coaxial fibers for high performance yarn supercapacitors. J Mater Chem A 2017; 5: 22489–22494.

28.

Wang

Tian

Gao

et al. Diversified constructions and electrochemical cycling stability of metal oxide fiber supercapacitors. J Mater Res Technol 2023; 24: 909–917.

29.

Zhang

Zhao

Zhang

et al. Construction of flexible fiber boron-doped diamond film and its supercapacitor application. J Colloid Interface Sci 2022; 629: 813–821.

30.

Zhang

Zhao

Zhang

et al. Preparation of nanowires on free-standing boron-doped diamond films for high performance micro-capacitors. Electrochim Acta 2022; 421: 140500.

31.

Liu

Gao

et al. A systematic investigation for mode-I fracture properties of stitched composites. Int J Mech Sci 2023; 241: 107982.

32.

Yao

Dou

Liu

et al. Micro- and nano-scale mechanisms of enzymatic treatment on the interfacial behaviors of sisal fiber reinforced bio-based epoxy resin. Ind Crop Prod 2023; 194: 116319.

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