Abstract
Solvothermal reactions of Zn(NO3)2·6H2O, 1,4-benzenedicarboxylic acid (H2BDC) and 2,4,6-tris(pyrazol-1-yl)-1,3,5-s-triazine, yielded a new coordination polymer [Zn(BDC)(pz)·H2O]n (pz= pyrazole). The in situ methanolysis reaction of 2,4,6-tris(pyrazol-1-yl)-1,3,5-s-triazine with pyrazole and 2,4,6-trismethoxy-1,3,5-triazine was confirmed by their single-crystal structures. [Zn(BDC)(pz)·H2O]n was characterised by elemental analysis, IR, powder X-ray diffraction, photoluminescence and thermogravimetric analyses.
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