Abstract
The dinuclear Mn(II) complex [Mn2(L)2(bipy)4]·(ClO4)2·3H2O (HL = 2-benzothiazolylthioacetic acid; bipy = 2,2'-bipyridine) has been synthesised and characterised by single crystal X-ray diffraction, IR and elemental analysis. In the dimeric, cationic complex with a crystallographic centre of symmetry, two bipy molecules chelate each Mn atom. These two metal fragments are then bridged by two L groups in a syn–anti conformation with a Mn···Mn distance of 4.767 Å. The arrangement of these dimers allows the formation of tunnels that host the ClO4- anions and lattice water molecules through hydrogen bonds. Magnetic susceptibility measurement revealed antiferromagnetic coupling between the metal centres.
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