Abstract
The crystal structure of a new Cu(II) carboxylato-bridged complex [Cu(L)(SCN)]n (1) [where HL = 2-N-(2′-pyridylimine)benzoic acid] forms a helical chain polymer chain. In 1, adjacent copper atoms are linked by carboxylate groups in a syn–anti conformation. The title complex was also characterised by elemental analysis, IR spectra, electronic spectra and variable temperature magnetic measurements.
Keywords
References
1.
Kahn O.
, Angew Chem., Int. Ed. Engl. , 1985 , 24 , 834 .
2.
Kahn O.
, Struct. Bonding (Berlin) 1987 , 68 , 89 .
3.
Gatteschi D.
,
Kahn O.
,
Miller J. S.
, and
Palacio F.
(eds.), Magnetic Molecular Materials , NATO ASI Series E198, Kluwer , Dordrecht , 1991 .
4.
Triller M.U.
,
Hsieh W. Y.
,
Pecoraro V. L.
,
Rompel A.
, and
Krebs B.
, Inorg. Chem. , 2002 , 41 5544 ; V.L. Pecoraro, Manganese Redox Enzymes ; Ed.; VCH: New York, 1992.
5.
Wieghardt K.
, Angew. Chem., Int. Ed. Engl. , 1989 , 28 , 1153 .
6.
Que L.
Jr.
, and
True A.
, Prog. Inorg. Chem. , 1990 , 38 , 97 .
7.
Rardin R.L.
,
Tolman W. B.
, and
Lippard S. J.
, New. J. Chem. , 1991 , 417 .
8.
Orvan P.J.
,
Estes W. E.
,
Weller R. R.
, and
Hatfield W. E.
, Inorg. Chem. , 1980 , 19 , 1297 .
9.
Doedens R.J.
, Prog. Inorg. Chem. , 1976 , 21 , 209 .
10.
Rettig S.J.
,
Thompson R. C.
, and
Trotter J.
,
Xia S.
, Inorg. Chem. , 1999 , 38 , 1360 and references therein.
11.
Tangoulis V.
,
Psomas G.
,
Dendrinou-Samara C.
,
Raptopoulou C. P.
,
Terzis A.
, and
Kessissoglou D. P.
, Inorg. Chem. , 1996 , 35 , 7655 .
12.
Colacio E.
,
Domínguez-Vera J. M.
,
Ghazi M.
,
Kivekäs R.
,
Klinga M.
, and
Moreno J. M.
, Eur. J. Inorg. Chem. , 1999 , 441 and references therein.
13.
Colacio E.
,
Domínguez-Vera J. M.
,
Kivekäs R.
,
Moreno J. M.
,
Romerosa A.
, and
Ruiz J.
, Inorg. Chim. Acta , 1993 , 212 , 115 and references therein.
14.
Wang C.-C.
,
Yang C.-H.
,
Lee C.-H.
, and
Lee G.-H.
, Inorg. Chem. , 2002 , 41 , 429 .
15.
Nanda K.K.
,
Addison A. W.
,
Sinn E.
, and
Thompson L. K.
, Inorg. Chem. , 1996 , 35 , 5966 .
16.
Schulz D.
,
Weyhermüller T.
,
Wieghartdt K.
,
Butzlaff C.
, and
Trautwein A. X.
, Inorg. Chim. Acta , 1996 , 247 , 387 .
17.
Sen S.
,
Saha M. K.
,
Gupta T.
,
Karmakar A. K.
,
Kundu P.
,
Mitra S.
,
Hursthouse M. B.
, and
Malik K. M. A.
, J. Chem. Crystallogr. , 1998 , 28 , 771 .
18.
Dey S.K.
,
Bag B.
,
Malik K. M. A.
,
El Fallah M. S.
,
Ribas J.
, and
Mitra S.
, Inorg. Chem. , 2003 , 42 , 4029 .
19.
Colacio E.
,
Ghazi M.
,
Kivekäs R.
, and
Moreno J. M.
, Inorg. Chem. , 2000 , 39 , 2882 .
20.
Addison A.W.
,
Rao T. N.
,
Reedijk J.
,
Riju J. V.
, and
Verschoor C. G.
, J. Chem. Soc., Dalton Trans. , 1984 , 1349 .
21.
Nakamoto K.
, Infrared and Raman spectra of Inorganic and Coordination Compounds , 3rd edn, Wiley Interscience , New York, USA , 1978 , p. 233 .
22.
Atherton N.M.
,
Fenton D. E.
,
Hewson G. J.
, and
McLean C. H.
, J. Chem. Soc., Dalton Trans. , 1988 , 1059 .
23.
Lever A.B. P.
, Inorganic Electronic Spectroscopy , Elsevier Science , New York , 2nd edn, 1984 .
24.
Sheldrick G.M.
, SHELTXL. Version 5.1. Bruker AXS Inc. , Madison, Wisconsin, USA , 1999 .