Application of melt-blown technology in the manufacturing of a solvent vapor-sensitive,non-woven fabric composed of poly(lactic acid) loaded with multi-walled carbon nanotubes

Abstract

We evaluated a solvent vapor-sensitive, non-woven fabric made from a biodegradable, poly(lactic acid) (PLA) polymer loaded with multi-walled carbon nanotubes. The sensory properties of the fabric were obtained by optimizing the process parameters for manufacturing the melt-blown, non-woven fabric composed of 98% PLA 4060D (Nature Works) and 2% multi-walled carbon nanotubes (Nanocyl®). The diffusion of polar and non-polar solvent molecules influenced the electron flow between the separated carbon nanotubes in percolation paths built into the PLA, resulting in an increase of the resistance of the melt-blown, non-woven fabrics. The statistically significant differences between the mean values of electrical resistance before and after the influence of the tested solvent vapors were achieved for the non-woven fabrics manufactured at high air velocity and low extruder screw speed, taking the values of 30 m³/h and 20 rpm, respectively. The results obtained for the non-woven fabric manufactured in the optimal conditions show that methanol vapor response has the lowest amplitude of 15%, whereas for benzene, acetone and toluene sensitivity reaches values of 60%, 40%, and 35%, respectively. The values of the relative resistance amplitude correspond with Flory–Huggins interaction parameters κ_PLA\benzene < κ_PLA\acetone < κ_PLA\toluene < κ_{PLA\methanol.}