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Abstract

The novel nano lead(II) coordination compound [Pb(p-2-minh)₂] (1) (p-2-minh=pyridin-2-ylmethylene-isonicotinohydrazide) was synthesized by a sonochemical method. The new nano structure was characterized by using scanning electron microscopy (SEM), X-ray powder diffraction, elemental analysis, and thermal analysis. The single-crystal X-ray structure shows that the overall structure of 1 is a discrete coordination compound. This is further extended into a three-dimensional (3-D) supramolecular structure by π - π and other weak directional intermolecular interactions. The coordination number of the Pb(II) ions is six, PbN₄O₂. The PbO nanoparticles were obtained by the thermolysis of 1 at 180°C with oleic acid as a surfactant. The average diameter of the nanoparticles was estimated by the Scherrer equation to be 18 nm. The morphology and size of the prepared PbO samples were further observed using SEM.

Keywords

Nano coordination compound ultrasonic supramolecular interaction nano lead(II) oxide

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Stereochemically active lone pair on lead(II) nano 3D supramolecular network: Synthesis,structural characterization,thermal stability and DFT calculation of [Pb(p-2-minh) 2 ]

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