Abstract
The influence of the preparation conditions on the structures of mesoporous molecular sieve MCM-41 were studied. The prepared MCM-41 samples were characterised by nitrogen physical adsorption–desorption, powder X-ray diffraction, transmission electron microscopy, FT-IR spectroscopy, thermo gravimetric analysis, differential scanning calorimetry and water/benzene static adsorption technologies. Ru/MCM-41 catalysts were then prepared by double solvent impregnation method and tested for benzene hydrogenation to cyclohexene. The structure characteristics of MCM-41 have a great effect on cyclohexene selectivity in benzene hydrogenation process. Ruthenium supported on MCM-41 with moderate surface area, larger pore size and pore volume, better long-range-order of hexagonal mesoporous shows better catalytic performance for benzene hydrogenation to cyclohexene.
References
1.
Melgo M.S.
,
Lindner A.
, and
Schuchardt U.
, Appl. Catal. A: Gen. , 2004 , 273 , 217 .
2.
Sato K.
,
Aoki M.
, and
Noyori R.
, Science , 1998 , 281 , 1646 .
3.
Chen Y.W.
, and
Hu S.C.
, European Patent 1048349A1 to Chinese Petroleum Corporation, 1999 .
4.
Hartog F.
, and
Zwietering P.
, J. Catal. , 1963 , 2 , 79 .
5.
Nagahara H.
, and
Konishi M.
, US Patent 4734536 to Asahi Kasei Kogyo Kabushiki Kaisha, 1988 .
6.
Abu Bakar N.H.H.
,
Bettahar M.M.
,
Abu Bakar M.
,
Monteverdi S.
, and
Ismail J.
, J. Mol. Catal. A: Chem. , 2010 , 333 , 11 .
7.
Kluson P.
, and
Cerveny L.
, Appl. Catal. A: Gen. , 1995 , 128 , 13 .
8.
Liu Z.
,
Dai W.L.
,
Liu B.
, and
Deng J.F.
, J. Catal. , 1999 , 187 , 253 .
9.
Liu S.C.
,
Wu Y.M.
,
Wang Z.
,
Zhao S.H.
,
Huang Z.X.
, and
Liu Y.L.
, J. Nat. Gas Chem. , 2005 , 14 , 226 .
10.
Liu S.C.
,
Liu Z.Y.
,
Liu Y.L.
,
Wu Y.M.
,
Wang Z.
, and
Zhu W.N.
, J. Rare Earths. , 2006 , 24 , 456 .
11.
Odenbrand C.U.I.
, and
Andersson S.L.T.
, J. Chem. Technol. Biotechnol. , 1982 , 32 , 365 .
12.
Struijk J.
, and
Scholten J.J.F.
, Appl. Catal. A: Gen. , 1992 , 82 , 277 .
13.
Hu S.C.
, and
Chen Y.W.
, Ind. Eng. Chem. Res. , 2001 , 40 , 3127 .
14.
Hu S.C.
, and
Chen Y.W.
, Ind. Eng. Chem. Res. , 2001 , 40 , 6099 .
15.
Milone C.
,
Neri G.
,
Donato A.
,
Musolino M.G.
, and
Mercadante L.
, J. Catal. , 1996 , 159 , 253 .
16.
Rodrigues M.F.F.
, and
Cobo A.J.G.
, Catal. To day , 2010 , 149 , 321 .
17.
Suryawanshi P.T.
, and
Mahajani V.V.
, J. Chem. Technol. Biotechnol. , 1997 , 69 , 154 .
18.
Wang J.Q.
,
Wang Y.Z.
,
Xie S.H.
,
Qiao M.H.
,
Li H.X.
, and
Fan K.N.
, Appl. Catal. A: Gen. , 2004 , 272 , 29 .
19.
Ronchin L.
, and
Toniolo L.
, Catal. Today , 2001 , 66 , 363 .
20.
Liu H.Z.
,
Liang S.G.
,
Wang W.T.
,
Jiang T.
, and
Han B.X.
, J. Mol. Catal. A: Chem. , 2011 , 341 , 35 .
21.
Zonetti P.C.
,
Landers R.
, and
Cobo A.J.G.
, Appl. Surf. Sci. , 2008 , 254 , 6849 .
22.
Ronchin L.
, and
Toniolo L.
, React. Kinet. Catal. Lett. , 2003 , 78 , 281 .
23.
Zhao Y.J.
,
Zhou J.
,
Zhang J.G.
, and
Wang S.D.
, Catal. Commun. , 2008 , 9 , 459 .
24.
Struijk J.
,
d'Angremond M.
,
Lucas-de Regt W.J.M.
, and
Scholten J.J.F.
, Appl. Catal. A: Gen. , 1992 , 83 , 263 .
25.
Wang W.T.
,
Liu H.Z.
,
Wu T.B.
,
Zhang P.
,
Ding G.D.
,
Liang S.G.
,
Jiang T.
, and
Han B.X.
, J. Mol. Catal. A: Chem. , 2012 , 355 , 174 .
26.
Bu J.
,
Pei Y.
,
Guo P.J.
,
Qiao M.H.
,
Yan S.R.
, and
Fan K.N.
, Recent progress in mesostructured materials , eds
Zhao D.
,
Qiu S.
,
Tang Y.
, and
Yu C.
, Elsevier , Shanghai , 2006 . Vol. 165 , pp. 769 .
27.
Liu S.C.
,
Liu Z.Y.
,
Wang Z.
,
Zhao S.H.
, and
Wu Y.M.
, Appl. Catal. A: Gen. , 2006 , 313 , 49 .
28.
Xue W.
,
Zhao Q.Q.
,
Wang D.D.
,
Du W.M.
, and
Wang Y.J.
, Acta Petrol. Sinica (Petroleum Processing Section) , 2009 , 25 , 120 .
29.
Xue W.
,
Zhao Q.
,
Yuan B.
,
Li F.
, and
Wang Y.
, Acta Petrol. Sinica (Petroleum Processing Section) , 2012 , 28 , 47 .
30.
Bu J.
,
Liu J.L.
,
Chen X.Y.
,
Zhuang J.H.
,
Yan S.R.
,
Qiao M.H.
,
He H.Y.
, and
Fan K.N.
, Catal. Commun. , 2008 , 9 , 2612 .
31.
Liu J.L.
,
Zhu L.J.
,
Pei Y.
,
Zhuang J.H.
,
Li H.
,
Li H.X.
,
Qiao M.H.
, and
Fan K.N.
, Appl. Catal. A: Gen. , 2009 , 353 , 282 .
32.
Liu J.L.
,
Zhu Y.
,
Liu J.
,
Pei Y.
,
Li Z.H.
,
Li H.
,
Li H.X.
,
Qiao M.H.
, and
Fan K.N.
, J. Catal. , 2009 , 268 , 100 .
33.
Liao H.G.
,
Zhang J.
,
Liu P.L.
,
Hao F.
,
You K.Y.
, and
Luo H.A.
, Synth. React. Inorg. M. , 2013 , 43 , 1206 .
34.
Tanev P.T.
, and
Pinnavaia T.J.
, Science , 1995 , 267 , 865 .
35.
Grün M.
,
Unger K.K.
,
Matsunoto A.
, and
Tsutsumi K.
, Micropor. Mesopor. Mat. , 1999 , 27 , 207 .
36.
Zhao D.
,
Feng J.
,
Huo Q.
,
Melosh N.
,
Fredrickson G.H.
,
Chmelka B.F.
, and
Stucky G.D.
, Science , 1998 , 279 , 548 .
37.
Beck J.S.
,
Vartuli J.C.
,
Roth W.J.
,
Leonowicz M.E.
,
Kresge C.T.
,
Schmitt K.D.
,
Chu C.T.W.
,
Olson D.H.
,
Sheppard E.W.
,
McCullen S.B.
,
Higgins J.B.
, and
Schlenker J.L.
, J. Am. Chem. Soc. , 1992 , 114 , 10834 .
38.
Kresge C.T.
,
Leonowicz M.E.
,
Roth W.J.
,
Vartuli J.C.
, and
Beck J.S.
, Nature , 1992 , 359 , 710 .
39.
Mizukami F.
,
Niwa S.
,
Toba M.
,
Tsuchiya T.
,
Shimizu K.
,
Imai S.
, and
Imamura J.
, Preparation of catalysts I V: scientific bases for the preparation of heterogeneous catalysts , eds
Delmon B.
,
Grange P.
,
Jacobs P.A.
, and
Poncelet G.
, Elsevier , Ibaraki , 1987 . Vol. 31 , pp. 45 .
40.
Niwa S.I.
,
Mizukami F.
,
Isoyama S.
,
Tsuchiya T.
,
Shimizu K.
,
Imai S.
, and
Imamura J.
, J. Chem. Tech. Biotechnol. , 1986 , 36 , 236 .
41.
Huo Q.
,
Margolese D.I.
,
Ciesla U.
,
Demuth D.G.
,
Feng P.
,
Gier T.E.
,
Sieger P.
,
Firouzi A.
,
Chmelka B.F.
,
Schüth F.
, and
Stucky G.D.
, Chem. Mater. , 1994 , 6 , 1176 .
42.
Chen P.
,
Mao J.P.
,
Ma H.F.
,
Ma J.H.
, and
Li R.F.
, Acta Petrol. Sinica (Petroleum Processing Section) , 2006 , 22 , 7 .
43.
Tian P.
,
Blanchard J.
,
Fajerwerg K.
,
Breysse M.
,
Vrinat M.
, and
Liu Z.
, Micropor. Mesopor. Mat. , 2003 , 60 , 197 .
44.
Lin W.
,
Cai Q.
,
Pang W.
,
Yue Y.
, Chem. Commun. , 1998 , 22 , 2473 .