Zeolite Mediated Reactions: Mechanistic Aspects and Environmental Applications

Abstract

An overview is presented of basic research and applications for the use of zeolites in environmentally-related topics. The use of these materials to promote oxidation reactions, and other catalytic processes is surveyed along with ship-in-a-bottle synthesis of particular zeolite-encapsulated catalysts. Methods for probing the surfaces of zeolites using spin-probes and ESR detection are mentioned. The ability of some thermally activated zeolites to produce spontaneously radical cations by single-electron oxidation of organic molecules is reviewed. The issue of the degree of acidity of H-zeolites is discussed, which demonstrates them not to be super-acids. Some ESR determinations of the adsorption of NO_x species onto selected zeolites are reviewed and the use of zeolites to catalyse desulfurisation of hydrocarbons is considered. Finally, there is mention made of the use of zeolites to catalyse hydrodechlorination of CFC's and other organic chlorine-containing compounds. Surfactant-modified zeolites (SMZ) for use as polyfunctional decontamination agents are further discussed. Theoretical methods, e.g. Density Functional Theory (DFT), are finding their own application to studying the mechanisms of reactions that are mediated by zeolites as is shown throughout.