Free accessResearch articleFirst published online 2007-7
A One-Pot,Stereoselective Synthesis of ( Z )-1,2-disubstituted Vinyl Sulfides by Sequential Hydrostannylation and Stille reaction of Acetylenic Sulfides with Tributyltin Hydride and then with aryl iodides
(Z)-1,2-Disubstituted vinyl sulfides can be stereoselectively synthesised in one pot under mild conditions, in good yields, by the palladium-catalysed hydrostannylation of acetylenic sulfides, followed by Stille coupling with aryl iodides.
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