Abstract
The Stille coupling of (E)-α-stannylvinyl sulfones with alkynyl bromides in DMF in the presence of Pd(PPh3)4 and CuI gave (Z)-2-sulfonyl-1,3-enynes in good yields. (Z)-2-Sulfonyl-1,3-enynes underwent palladium-catalysed hydrostannylation with tributyltin hydride to afford highly regio- and stereoselectively (1Z,3E)-2-sulfonyl-3-stannyl-1,3-dienes.
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