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Abstract

We carefully tailored a porous silicon (pSi) surface by oxidation with hydrogen peroxide (H₂O₂) to determine the time-dependent changes in nano-crystallite surface chemistries (e.g., Si–O-Si, SiH_x [x = 1,2], O_ySiH [y=2,3], and SiOH/H₂O) and their influence on the pSi photoluminescence (PL). The relationship between infrared band amplitudes and PL intensity were evaluated under H₂O₂ and O₃ (previously studied) oxidation. The pSi surface composition under O₃ and H₂O₂ oxidation conditions tended to, save the O_ySiH (y=2,3) species, approach similar values at the longest oxidation times studied, but they took very different paths in reaching these end points. Furthermore, the pSi surface compositions that exhibit maximum/minimum PL under each oxidant are very different.

Keywords

Porous silicon Hydrogen peroxide Ozone Photoluminescence Infrared Correlation

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References

Buriak

. Porous Silicon. New York, NY: John Wiley and Sons, 2001.

Cullis

A.G.

Canham

L.T.

Calcott

P.D.J.

. “The Structural and Luminescence Properties of Porous Silicon”. J. Appl. Phys. 1997. 82(3): 909–965. doi:10.1063/1.366536.

Granitzer

Rumpf

. “Porous Silicon-A Versatile Host Material”. Materials. 2010. 3(2): 943–998. doi:10.3390/Ma3020943.

Mattei

Yakovlev

V.A.

. “Porous Silicon Superstructures and Their Application in Optical Spectroscopy”. Recent Res. Dev. Mater. Sci. Eng. 2002. 1: 511–526.

Miller

B.L.

. “Porous Silicon in Biosensing Applications”. Opt. Sci. Eng. 2007. 118(1): 271–290.

Torres-Costa

Martin-Palma

R.J.

. “Application of Nanostructured Porous Silicon in the Field of Optics. A Review”. J. Mater. Sci. 2010. 45(11): 2823–2838. doi:10.1007/s10853-010-4251-8.

Badilla

J.P.

Rojas

D.C.

Lopez

Fahlman

B.D.

Ramirez-Porras

. “Development of an Organic Vapor Sensor Based on Functionalized Porous Silicon”. Phys. Status Solidi A. 2011. 208(6): 1458–1461. doi:10. 1002/pssa.201000036.

Jane

Dronov

Hodges

Voelcker

N.H.

. “Porous Silicon Biosensors on the Advance”. Trends Biotechnol. 2009. 27(4): 230–239. doi:10.1016/j.tibtech.2008.12.004.

Q.S.

Zhang

R.Q.

Lee

S.T.

Niehaus

T.A.

Frauenheim

. “Optimal Surface Functionalization of Silicon Quantum Dots”. J. Chem. Phys. 2008. 128(24): 244714. doi:10.1063/1.2940735.

10.

Mulloni

Pavesi

. “Porous Silicon Microcavities as Optical Chemical Sensors”. Appl. Phys. Lett. 2000. 76(18): 2523. doi:10.1063/1.126396.

11.

Pacholski

Sailor

M.J.

. “Sensing with Porous Silicon Double Layers: A General Approach for Background Suppression”. Phys. Status Solidi C. 2007. 4(6): 2088–2092. doi:10.1002/pssc.200674381.

12.

Sailor

M.J.

. “Color Me Sensitive: Amplification and Discrimination in Photonic Silicon Nanostructures”. ACS Nano. 2007. 1(4): 248–252. doi:10. 1021/nn700340u.

13.

Sailor

M.J.

Link

J.R.

. “Smart Dust: Nanostructured Devices in a Grain of Sand”. Chem. Commun. 2005. 11: 1375–1383. doi:10.1039/b417554a.

14.

Singh

Sharma

S.N.

Ravindra

N.M.

. “Applications of Porous Silicon Thin Films in Solar Cells and Biosensors”. JOM. 2010. 62(6): 15–24. doi:10.1007/s11837-010-0099-2.

15.

Jaguiro

Katsuba

Lazarouk

Smirnov

. “Porous Silicon Avalanche LEDs and Their Applications in Optoelectronics and Information Displays”. Acta Phys. Pol. A. 2007. 112(5): 1031–1036.

16.

Canham

L.T.

. “Laser-Dye Impregnation of Oxidized Porous Silicon on Silicon-Wafers”. Appl. Phys. Lett. 1993. 63(3): 337–339. doi:10.1063/1. 110035.

17.

Linnros

. “Optoelectronics: Nanocrystals Brighten Transistors”. Nat. Mater. 2005. 4(2): 117–119. doi:10.1038/nmat1318.

18.

Martinez-Duart

J.M.

Martin-Palma

R.J.

. “Photodetectors and Solar Cells Based on Porous Silicon”. Phys. Status Solidi B. 2002. 232(1): 81–88. doi:10.1002/1521-3951(200207)232:1.

19.

Holmes

J.D.

Ziegler

K.J.

Doty

R.C.

Pell

L.E.

Johnston

K.P.

Korgel

B.A.

. “Highly Luminescent Silicon Nanocrystals with Discrete Optical Transitions”. J. Am. Chem. Soc. 2001. 123(16): 3743–3748. doi:10.1021/ja002956f.

20.

Hua

Swihart

M.T.

Ruckenstein

. “Efficient Surface Grafting of Luminescent Silicon Quantum Dots by Photoinitiated Hydrosilylation”. Langmuir. 2005. 21(13): 6054–6062. doi:10.1021/la0509394.

21.

Kirkey

W.D.

Sahoo

X.G.

Y.Q.

Swihart

M.T.

Cartwright

A.N.

Bruckenstein

Prasad

P.N.

. “Quasi-reversible Photoluminescence Quenching of Stable Dispersions of Silicon Nanoparticles”. J. Mater. Chem. 2005. 15(20): 2028–2034. doi:10.1039/B417648k.

22.

X.G.

Y.Q.

Talukdar

S.S.

Swihart

M.T.

. “Process for Preparing Macroscopic Quantities of Brightly Photoluminescent Silicon Nanoparticles with Emission Spanning the Visible Spectrum”. Langmuir. 2003. 19(20): 8490–8496. doi:10.1021/La034487b.

23.

Z.F.

Swihart

M.T.

Ruckenstein

. “Luminescent Silicon Nanoparticles Capped by Conductive Polyaniline through the Self-Assembly Method”. Langmuir. 2004. 20(5): 1963–1971. doi:10.1021/La0358926.

24.

Swihart

M.T.

. “Surface Functionalization of Silicon Nanoparticles Produced by Laser-Driven Pyrolysis of Silane Followed by HF-HNO₃ Etching”. Langmuir. 2004. 20(11): 4720–4727. doi:10.1021/la036219j.

25.

Siu

G.G.

X.L.

Bao

X.M.

. “Enhanced and Stable Photoluminescence from Partially Oxidized Porous Si Coated with Si Thin Films”. J. Appl. Phys. 2000. 88(6): 3781–3783. doi:10.1063/1. 1289787.

26.

Dulcey

C.S.

Georger

J.H.

Jr. Krauthamer

Stenger

D.A.

Fare

T.L.

Calvert

J.M.

. “Deep UV Photochemistry of Chemisorbed Monolayers: Patterned Coplanar Molecular Assemblies”. Science. 1991. 252(5005): 551–554. doi:10.1126/science.2020853.

27.

H.L.

Zhu

Y.C.

D.S.

Wan

Xia

Zhao

X.S.

. “Vapor-phase Silanization of Oxidized Porous Silicon for Stabilizing Composition and Photoluminescence”. J. Appl. Phys. 2009. 105(11): 114307/114301–114307/114307. doi:10.1063/1.3133209.

28.

Cullis

A.G.

Canham

L.T.

Williams

G.M.

Smith

P.W.

Dosser

O.D.

. “Correlation of the Structural and Optical-Properties of Luminescent, Highly Oxidized Porous Silicon”. J. Appl. Phys. 1994. 75(1): 493–501. doi:10.1063/1.355827.

29.

Gelloz

Koshida

. “Mechanism of a Remarkable Enhancement in the Light Emission from Nanocrystalline Porous Silicon Annealed in High-Pressure Water Vapor”. J. Appl. Phys. 2005. 98(12): 123509/123501–123509/123507. doi:10.1063/1.2147847.

30.

Ligeon

Muller

Herino

Gaspard

Vial

J.C.

Romestain

Billat

Bsiesy

. “Analysis of the Electroluminescence Observed During the Anodic-Oxidation of Porous Layers Formed on Lightly P-Doped Silicon”. J. Appl. Phys. 1993. 74(2): 1265–1271. doi:10.1063/1.354930.

31.

Dorn

Lüth

Ibach

. “The Adsorption of Oxygen on Silicon (111) Surfaces. II”. Surf. Sci. 1974. 42(2): 583–594. doi:10.1016/0039-6028(74)90041-7.

32.

Fink

C.K.

Nakamura

Ichimura

Jenkins

S.J.

. “Silicon Oxidation by Ozone”. J. Phys. Condens. Matter. 2009. 21(18): 183001. doi:10.1088/0953-8984/21/18/183001.

33.

Belyakov

L.V.

Goryachev

D.N.

Sreseli

O.M.

Yaroshetskii

I.D.

. “Efficient Electroluminescence of Porous Silicon”. Semiconductors. 1993. 27(11-12): 999–1001.

34.

Caras

C.A.

Reynard

J.M.

Deuro

R.E.

Bright

F.V.

. “Link Between O₂SiH Infrared Band Amplitude and Porous Silicon Photoluminescence During Ambient O₃ Oxidation”. Appl Spectrosc. 2012. 66(8): 951–957. doi:10. 1366/12-06630.

35.

Mawhinney

D.B.

Glass

J.A.

Yates

J.T.

. “FTIR Study of the Oxidation of Porous Silicon”. J. Phys. Chem. B. 1997. 101(7): 1202–1206. doi:10.1021/Jp963322r.

36.

Dubin

V.M.

Ozanam

Chazalviel

J.N.

. “In-Situ Infrared Spectroscopic Study of Luminescent Porous Silicon”. Vib. Spectrosc. 1995. 8(2): 159–166. doi:10.1016/0924-2031(94)00035-F.

37.

Halls

M.D.

Raghavachari

. “Infrared Intensities of v(Si—H) on H/Si(100)-2X1: Effect of O Incorporation and Agglomeration”. J. Phys. Chem. B. 2004. 108(50): 19388–19391. doi:10.1021/jp046808d.

38.

Harper

Sailor

M.J.

. “Detection of Nitric Oxide and Nitrogen Dioxide with Photoluminescent Porous Silicon”. Anal. Chem. 1996. 68(21): 3713–3717. doi:10.1021/ac960642y.

39.

Niwano

Kageyama

Kinashi

Miyamoto

Honma

. “Infrared Spectroscopic Study of Initial-Stages of Ultraviolet Ozone Oxidation of Si(100) and Si(111) Surfaces”. J. Vac. Sci. Technol. A. 1994. 12(2): 465–470. doi:10.1116/1.579264.

40.

Stefanov

B.B.

Gurevich

A.B.

Weldon

M.K.

Raghavachari

Chabal

Y.J.

. “Silicon Epoxide: Unexpected Intermediate During Silicon Oxide Formation”. Phys. Rev. Lett. 1998. 81(18): 3908–3911. doi:10.1103/PhysRevLett.81.3908.

41.

Xie

Y.H.

Wilson

W.L.

Ross

F.M.

Mucha

J.A.

Fitzgerald

E.A.

Macaulay

J.M.

Harris

T.D.

. “Luminescence and Structural Study of Porous Silicon Films”. J. Appl. Phys. 1992. 71(5): 2403–2407. doi:10.1063/1. 351097.

42.

Warner

I.M.

Davidson

E.R.

Christian

G.D.

. “Quantitative Analyses of Multicomponent Fluorescence Data by the Methods of Least Squares and Non-Negative Least Sum of Errors”. Anal. Chem. 1977. 49(14): 2155–2159. doi:10.1021/ac50022a015.

43.

Butturi

M.A.

Carotta

M.C.

Martinelli

Passari

Youssef

G.M.

Chiorino

Ghiotti

. “Effects of Ageing on Porous Silicon Photoluminescence: Correlation with FTIR and UV-Vis Spectra”. Solid State Commun. 1997. 101(1): 11–16. doi:10.1016/s0038-1098(96)00539-x.

44.

Fukuda

Furuya

Ishikawa

Saito

. “Aging Behavior of Photoluminescence in Porous Silicon”. J. Appl. Phys. 1997. 82(11): 5718–5721. doi:10.1063/1.366435.

45.

Koch

Petrova-Koch

Muschik

Nikolov

Gavrilenko

. “Some Perspectives on the Luminescence Mechanism via Surface-Confined States of Porous Silicon”. Mater. Res. Soc. Symp. Proc. 1993. 283: 197–202.

46.

Koropecki

Arce

Schmidt

. “Photo-Oxidation Effects in Porous Silicon Luminescence”. Phys. Rev. B. 2004. 69(20): 205317/205311–205317/205316. doi:10.1103/PhysRevB.69.205317.

47.

Kumar

Kitoh

Hara

. “Effect of Surface-Treatment on Visible Luminescence of Porous Silicon - Correlation with Hydrogen and Oxygen Terminators”. Appl. Phys. Lett. 1993. 63(22): 3032–3034. doi:10.1063/1. 110249.

48.

Qin

G.G.

Jia

Y.Q.

. “Mechanism of the Visible Luminescence in Porous Silicon”. Solid State Commun. 1993. 86(9): 559–563. doi:10.1016/0038-1098(93)90139-E.

An In-Depth Study Linking the Infrared Spectroscopy and Photoluminescence of Porous Silicon during Ambient Hydrogen Peroxide Oxidation

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