Abstract
An approach utilizing diffuse reflectance FT-IR is described whereby the desorption of carbon monoxide from a pigment surface is correlated with the adsorption of two organo-functional silane materials, 3-chloropropylsilane (CPS) and 3-methacryloxypropyltrimethoxysilane (MPS). Correlation of observables from a single set of measurements provides an efficient means to determine the results of adsorption as a function of adsorbate structure and treatment solution concentration.
Get full access to this article
View all access options for this article.
References
1.Am. Paints and Coatings Journal 28 (1985 ).
2.
Ishida
H.
and
Koenig
J. L.
, J. Colloid Interface Sci. 64 , 565 (1978 ).
3.
Ishida
H.
and
Koenig
J. L.
, J. Polym. Sci., Poly. Phys. Ed. 17 , 615 (1979 ).
4.
Moses
P. R.
Wier
L. M.
Lennox
J. C.
Finklea
H. O.
Lennard
J. R.
, and
Murray
R. W.
, Anal. Chem. 50 , 576 (1978 ).
5.
Gettings
M.
and
Kinloch
A. J.
, J. Mater. Sci. 12 , 2511 (1977 ).
6.
Culler
S. R.
Ishida
H.
, and
Koenig
J. L.
, Ann. Rev. Mater. Sci. 13 , 363 (1983 ).
7.
Ishida
H.
, Polymer Composites 5 , 101 (1984 ).
8.
Ishida
H.
Naviroj
S.
Tripathy
S. K.
Fitzgerald
J. J.
, and
Koenig
J. L.
, J. Polym. Sci., Phys. Ed. 20 , 701 (1982 ).
9.
McKenzie
M. T.
Culler
S. R.
, and
Koenig
J. L.
, Appl. Spectrosc. 38 , 786 (1984 ).
10.
Uram
K. J.
Ng
Lily
Folman
M.
, and
Yates
J. T.
Jr.
, J. Chem. Phys. 84 , 2891 (1986 ).
11.
Urban
M. W.
and
Koenig
J. L.
, Appl. Spectrosc. 39 , 1051 (1985 ).
12.
Ishida
H.
Naviroj
S.
, and
Koenig
J. L.
, Physicochemical Aspects of Polymer Surfaces ,
Mittal
K. L.
, Ed. (Plenum , New York , 1983 ), p. 91 .
13.
McKenzie
M. T.
and
Koenig
J. L.
, Appl. Spectrosc. 39 , (1983 ).
14.
McKenzie
M. T.
, unpublished work.