With the growing demand for sustainable energy, electrochemical energy storage, particularly lithium-based batteries, is crucial. While graphite anodes are widely used, their low theoretical capacity (∼372 mAh g−1) limits energy density. Silicon emerges as a promising alternative due to its tenfold higher capacity, but its practical application is hindered by severe volume expansion (up to 400%) during lithiation, leading to electrode degradation. This paper reviews silicon anodes, focusing on optimization strategies to enhance their performance. Key factors such as binders and electrolytes significantly influence anode stability and efficiency. By carefully selecting adhesives and electrolytes during electrode design, the detrimental effects of volume expansion can be mitigated, improving cycling stability and capacity retention. The study highlights the importance of material combinations in manufacturing to achieve superior anode performance, offering insights into advancing silicon-based batteries for next-generation energy storage solutions.
ZubiGDufo-lópezRCarvalhoM, et al.The lithium-ion battery: state of the art and future perspectives. Renew Sustain Energy Rev2018; 89: 292–308. doi: https://doi.org/10.1016/j.rser.2018.03.002
2.
RangarajanSS, et al.Clean technologies lithium-ion batteries – the crux of electric vehicles with opportunities and challenges. Clean Technol2022; 4: 908–930.
3.
HossainHAsaduzzamanMHossainN, et al.Advances of lithium-ion batteries anode materials – a review. Chem Eng J Adv2023; 16: 100569.
4.
LinDLiuYCuiY. Reviving the lithium metal anode for high-energy batteries. Nat Nanotechnol2017; 12: 194–206.
5.
AsenbauerJChenZBresserD, et al.The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites. Sustain Energy Fuels2020; 4: 5387–5416.
GaslovSVRublevMSBiryukovAEKopytovSO. Virtual simulation of the operation of a lithium-ion battery as a part of a vehicle using 1D complex model. Transp Res Procedia2022; 68: 906–916. doi: https://doi.org/10.1016/j.trpro.2023.02.127
8.
MadaniSSZiebertCMarzbandM. Thermal behavior modeling of lithium-ion batteries: a comprehensive review. Symmetry (Basel)2023; 15: 1–37. doi: https://doi.org/10.3390/sym15081597
9.
FanE, et al.Sustainable recycling technology for Li-ion batteries and beyond: challenges and future prospects. Chem Rev2020; 120: 7020–7063.
10.
KoechAKMwandilaGMulolaniF, et al.Lithium-ion battery fundamentals and exploration of cathode materials: a review. South African J Chem Eng2024; 50: 321–339.
11.
ChenY, et al.A review of lithium-ion battery safety concerns: the issues, strategies, and testing standards. J Energy Chem2021; 59: 83–99.
12.
ChenaZXiongbRLuaJ, et al.Temperature rise prediction of lithium-ion battery suffering external short circuit for all-climate electric vehicles application. Appl Energy2018; 213: 375–383.
13.
SkeeteJWellsPDongX, et al.Energy research & social science beyond the EVent horizon: battery waste, recycling, and sustainability in the United Kingdom electric vehicle transition. Energy Res Soc Sci2020; 69: 101581.
14.
HouP, et al.Improving Li+ kinetics and structural stability of nickel-rich layered cathodes by heterogeneous inactive-Al3+ doping. ACS Sustain Chem Eng2018; 6: 5653–5661.
15.
WuWWangSWuW, et al.A critical review of battery thermal performance and liquid based battery thermal management. Energy Convers Manag2019; 182: 262–281.
16.
CasimirAZhangHOgokeO, et al.Silicon-based anodes for lithium-ion batteries: effectiveness of materials synthesis and electrode preparation. Nano Energy2016; 27: 359–376.
17.
YarmolichD, et al.Novel binder-free carbon anode for high capacity Li-ion batteries. Nano Energy2021; 83: 105816.
18.
SaddiqueJ, et al.Opportunities and challenges of nano Si/C composites in lithium ion battery: a mini review. J Alloys Compd2024; 978: 173507.
19.
TamiratAG, et al.Highly stable carbon coated Mg2Si intermetallic nanoparticles for lithium- ion battery anode. J Power Sources2018; 384: 10–17.
20.
LiuNTangQHuangB, et al.Graphene synthesis: method, exfoliation mechanism and large-scale production. Crystals2022; 12: 1–11.
ZhangH, et al.Gel electrolyte with flame retardant polymer stabilizing lithium metal towards lithium-sulfur battery. Energy Storage Mater2023; 61: 102885.
23.
WangCNakamuraHKomatsuH, et al.Electrochemical behaviour of a graphite electrode in propylene carbonate and 1,3-benzodioxol-2-one based electrolyte system. J Power Sources1998; 74: 142–145.
24.
YoshioMWangHFukudaK, et al.Effect of carbon coating on electrochemical performance of treated natural graphite as lithium-Ion battery anode material. J Electrochem Soc2000; 147: 1245.
25.
EshetuGG, et al.Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes. Nat Commun2021; 12: 1–14.
26.
ZhangX, et al.Stable high-capacity and high-rate silicon-based lithium battery anodes upon two-dimensional covalent encapsulation. Nat Commun2020; 11: –9.
27.
ChadhaU, et al.Theoretical progresses in silicon anode substitutes for lithium-ion batteries. J Energy Storage2022; 55: 105352.
28.
BowyerWNicholsJ. Philosophical Transactions of the Royal Society of London. 98th ed. London: Royal Society, 1808.
29.
StaufferRC. Speculation and experiment in the background of Oersted’s discovery of electromagnetism. Isis1957; 48: 33–50.
30.
XingZLuJJiX. A brief review of metallothermic reduction reactions for materials preparation. Small Methods2018; 2: 1–13.
31.
WöhlerF. Ueber künstliche Bildung des Harnstoffs. Ann Phys1828; 87: 253–256.
32.
SmithGD. From Monopoly to Competition: The Transformations of Alcoa, 1888–1986. 1st ed. Cambridge: Cambridge University Press, 2003.
33.
PlatacisEKaldreIBlumbergsE, et al.Titanium production by magnesium thermal reduction in the electroslag process. Sci Rep2019; 9: 1–13.
34.
BrooksGCookseyMWellwoodG, et al.Challenges in light metals production. Trans Inst Min Metall Sect C Miner Process Extr Metall2007; 116: 25–33.
35.
HasanH. Aluminum: Understanding the Elements of the Periodic Table. 1st ed. New York: The Rosen Publishing Group, Inc., 2006.
36.
PalUBWoolleyDEKenneyGB. Emerging SOM technology for the green synthesis of metals from oxides. JOM2001; 53: 32–35.
37.
TrescottM. The story behind the story: Julia B. Hall and aluminum. J Chem Educ1977; 54: 24–25.
38.
WisniakJ. Henri Étienne Sainte-Claire Deville: a physician turned metallurgist. J Mater Eng Perform2004; 13: 117–128.
39.
YasudaKSaegusaKOkabeTH. Aluminum subhalide as a reductant for metallothermic reduction. High Temp Mater Process2011; 30: 411–423.
40.
RasouliATsoutsouvaMSafarianJ, et al.Kinetics of magnesiothermic reduction of natural quartz. Materials (Basel)2022; 15. doi: https://doi.org/10.3390/ma15196535
41.
GiresanGSankaranarayananSRBerchmansLJ. Investigation on the thermodynamic analysis, preparation and characterization of LaNi5-hydrogen storage alloy by magnesiothermic reduction diffusion process. J Min Metall Sect B Metall2016; 52: 171–175. doi: https://doi.org/10.2298/jmmb150405015g
42.
TanZH, et al.Hydrogen generation via hydrolysis of Mg2Si. J Alloys Compd2019; 770: 108–115.
43.
AndriayaniA, RajaSLSihotangH, et al.Optimization of silicon extraction from Tanjung Tiram Asahan natural sand through magnesiothermic reduction. Int J Technol2015; 6: 1174–1183.
44.
SilvianaSMa’rufA. Silicon preparation derived from geothermal silica by reduction using magnesium. Int J Emerg Trends Eng Res2020; 8: 4861–4866.
45.
MatsubaraKShiomiHShionoT, et al.Porous silicon prepared from monolithic porous silica glass using a two-step magnesiothermic reduction. Int J Ceram Eng Sci2020; 2: 310–319.
46.
DaulayAAndriayaniAMarpongahtunM, et al.Scalable synthesis of porous silicon nanoparticles from rice husk with the addition of KBr as a scavenger agent during reduction by the magnesiothermic method as anode lithium-ion batteries with sodium alginate as the binder. South African J Chem Eng2022; 41: 203–210.
47.
FavorsZ, et al.Scalable synthesis of nano-silicon from beach sand for long cycle life Li-ion batteries. Sci Rep2014; 4: –7.
48.
HanP, et al.Morphology-controlled synthesis of hollow Si/C composites based on KI-assisted magnesiothermic reduction for high performance Li-ion batteries. Appl Surf Sci2019; 481: 933–939.
49.
LinN, et al.A low temperature molten salt process for aluminothermic reduction of silicon oxides to crystalline Si for Li-ion batteries. Energy Environ Sci2015; 8: 3187–3191.
50.
ZhouZWLiuYTXieXM, et al.Aluminothermic reduction enabled synthesis of silicon hollow microspheres from commercialized silica nanoparticles for superior lithium storage. Chem Commun2016; 52: 8401–8404.
51.
MishraK, et al.High performance porous Si@C anodes synthesized by low temperature aluminothermic reaction. Electrochim Acta2018; 269: 509–516.
52.
IslamMMSawahataJAkimotoK, et al.Formation of silicon layer through aluminothermic reduction of quartz substrates. Front Mater2022; 9: 1–12.
53.
PhilipssonHWallinMEinarsrudKE, et al.Kinetics of silicon production by aluminothermic reduction of silica using aluminum and aluminum dross as reductants. SSRN Electron J2021: 27–29. doi: https://doi.org/10.2139/ssrn.3922132
54.
ZhaoMYangSDongW. Low temperature aluminothermic reduction of natural sepiolite to high-performance Si nanofibers for Li-ion batteries. Front Chem2022; 10: 1–11.
55.
GaoP, et al.Formation of Si hollow structures as promising anode materials through reduction of silica in AlCl3–NaCl molten salt. ACS Nano2018; 12: 11481–11490.
56.
HouL, et al.Aluminothermic reduction synthesis of porous silicon nanosheets from vermiculite as high-performance anode materials for lithium-ion batteries. Appl Clay Sci2022; 218: 106418.
57.
CaiM, et al.Zincothermic reduction of silica to silicon: make the impossible possible. J Mater Chem A2021; 9: 21323–21331.
58.
KlugHPAlexanderLE. X-Ray Diffraction Procedures: For Polycrystalline and Amorphous Materials. 2nd ed. Harvard University, USA: Wiley-Interscience, 1974.
59.
MaY, et al.Silicon refining by solidification from liquid size alloy and floating zone method. Mater Trans2021; 62: 403–411.
60.
LiuX, et al.Scalable and cost-effective preparation of hierarchical porous silicon with a high conversion yield for superior lithium-ion storage. Energy Technol2016; 4: 593–599.
61.
ToliA, et al.Sustainable silicon and high purity alumina production from secondary silicon and aluminium raw materials through the innovative SisAl technology. Materials Proceedings2021: 1–6. doi: https://doi.org/10.3390/materproc2021005085
62.
FeyziEM RAKLiX, et al.A comprehensive review of silicon anodes for high-energy lithium-ion batteries: challenges, latest developments, and perspectives. Next Energy2024; 5: 100176.
63.
YuR, et al.Constructing sub 10 nm scale interfused TiO2/SiOx bicontinuous hybrid with mutual-stabilizing effect for lithium storage. ACS Nano2023; 17: 2568–2579.
64.
HuangWLiuSYuR, et al.Single-Atom lithiophilic sites confined within ordered porous carbon for ultrastable lithium metal anodes. Energy Environ Mater2023; 6. doi: https://doi.org/10.1002/eem2.12466
65.
BouguernMDAnil KumarMRZaghibK. The critical role of interfaces in advanced Li-ion battery technology: a comprehensive review. J Power Sources2024; 623: 235457. doi: https://doi.org/10.1016/j.jpowsour.2024.235457
66.
AnSJLiJDanielC, et al.The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling. Carbon NY2016; 105: 52–76.
67.
ZhangYShenHLiY, et al.Prelithiation strategies for enhancing the performance of lithium-ion batteries. RSC Adv2025; 15: 1249–1274.
68.
GaoT, et al.Enhanced cycling, safety and high-temperature performance of hybrid Li ion/Li metal batteries via fluoroethylene carbonate additive. Mater Chem Phys2024; 314: 128868.
69.
NieMAbrahamDPChenY, et al.Silicon solid electrolyte interphase (SEI) of lithium ion battery characterized by microscopy and spectroscopy. J Phys Chem C2013; 117: 13403–13412.
TokiGFIHossainMKRehmanWU, et al.Recent progress and challenges in silicon-based anode materials for lithium-ion batteries. Ind Chem Mater2024; 2: 226–269. doi: https://doi.org/10.1039/d3im00115f
73.
YuYZhengY. Effects of structural design, interface optimization, and processing on the performance of lithium battery anode silicon nanomaterials. ACE2025; 0: 202–206. doi: https://doi.org/10.54254/2755-2721/126/2025.20085
74.
LeeSKooHKangHS, et al.Advances in polymer binder materials for lithium-ion battery electrodes and separators. Polymers (Basel)2023; 15: 1–19.
75.
YoonJLeeJKimH, et al.Polymeric binder design for sustainable lithium-ion battery chemistry. Polymers (Basel)2024; 16. doi: https://doi.org/10.3390/polym16020254
HuangX, et al.Comparative study of vinylene carbonate and lithium difluoro(oxalate)borate additives in a SiOx/graphite anode lithium-ion battery in the presence of fluoroethylene carbonate. ACS Appl Mater Interfaces2025. doi: https://doi.org/10.1021/acsami.4c16779
78.
NogalesPM, et al.Stabilizing the solid electrolyte interphase of SiOx negative electrodes: the role of fluoroethylene carbonate in enhancing electrochemical performance. Batteries2024; 10. doi: https://doi.org/10.3390/batteries10110385
79.
LiuXZhuXPanD. Solutions for the problems of silicon–carbon anode materials for lithium-ion batteries. R Soc Open Sci2018; 5. doi: https://doi.org/10.1098/rsos.172370
80.
Muraleedharan PillaiMKalidasNZhaoXLehtoVP. Biomass-based silicon and carbon for lithium-ion battery anodes. Front Chem2022; 10: 1–11. doi: https://doi.org/10.3389/fchem.2022.882081
81.
ZhangX, et al.Strategies for controlling or releasing the influence due to the volume expansion of silicon inside Si–C composite anode for high-performance lithium-ion batteries. Materials2022; 15. doi: https://doi.org/10.3390/ma15124264
82.
LiangYZBhatALSuYS. Green synthesis of graphene flake/silicon composite anode for lithium-ion batteries using a ball-mill-derived mechanical transfer technique. ACS Appl Energy Mater2024. doi: https://doi.org/10.1021/acsaem.4c02183
83.
JohnJGangajaBNairSVSanthanagopalanD. Conformal coating of TiO2 shell on silicon nanoparticles for improved electrochemical performance in Li-ion battery applications. Electrochim Acta2017; 235: 191–199. doi: https://doi.org/10.1016/j.electacta.2017.03.127
84.
SunLLiuYShaoR, et al.Recent progress and future perspective on practical silicon anode-based lithium ion batteries. Energy Storage Mater2022; 46: 482–502. doi: https://doi.org/10.1016/j.ensm.2022.01.042
85.
WangZHuangTLiuZ, et al.Dopamine-modified carboxymethyl cellulose as an improved aqueous binder for silicon anodes in lithium-ion batteries. Electrochim Acta2021; 389: 138806.
86.
ZhengFTangZLeiY, et al.PAAS-β-CDp-PAA as a high-performance easily prepared and water-soluble composite binder for high-capacity silicon anodes in lithium-ion batteries. J Alloys Compd2023; 932. doi: https://doi.org/10.1016/j.jallcom.2022.167666
87.
ZhangSRenSHanD, et al.Aqueous sodium alginate as binder: dramatically improving the performance of dilithium terephthalate-based organic lithium ion batteries. J Power Sources2019; 438: 227007.
88.
SalsabilaAPrajatelistiaEPutroDY, et al.Exploring the feasibility of sodium alginate as a binder in aqueous zinc-ion batteries incorporating α-MnO2 nanorod cathodes. J Phys Chem Solids2024; 188. doi: https://doi.org/10.1016/j.jpcs.2024.111880
89.
YangD, et al.Sealing porous carbon via surface-initiated polymerization achieves low-surface-area Si–C microparticles for Li-ion batteries. Nano Energy2024; 127. doi: https://doi.org/10.1016/j.nanoen.2024.109744
90.
LiuD, et al.Novel conductive binder for high-performance silicon anodes in lithium ion batteries. Nano Energy2017; 36: 206–212. doi: https://doi.org/10.1016/j.nanoen.2017.04.043
91.
HowYYNumanAMustafaMN, et al.A review on the binder-free electrode fabrication for electrochemical energy storage devices. J Energy Storage2022; 51: 104324. doi: https://doi.org/10.1016/j.est.2022.104324
92.
TanW, et al.Rigid-flexible mediated Co-polyimide enabling stable silicon anode in lithium-ion batteries. Chem Eng J2024; 496: 153822.
TikekarMDChoudhurySTuZArcherLA. Design principles for electrolytes and interfaces for stable lithium-metal batteries. Nat Energy2016; 1: 1–7. doi: https://doi.org/10.1038/nenergy.2016.114
95.
DengD. Li-ion batteries: basics, progress, and challenges. Energy Sci Eng2015; 3: 385–418.
96.
HeP, et al.Solid-state batteries encounter challenges regarding the interface involving lithium metal. Nano Energy2024; 124: 109502.
97.
JeongWYunJLeeJ-W. Interfacial challenges and recent advances of solid-state lithium metal batteries. Bull Korean Chem Soc2024; 45(10), 80: 806–820.
98.
LeeYKimY-HAnJ-H, et al.Ionic conduction mechanisms in 70Li2S–30P2S5 type electrolytes experimental and atomic simulation studies. Acta Mater2022; 235. doi: https://doi.org/10.1016/j.actamat.2022.118106
99.
ZhouDShanmukarajDTkachevaA, et al.Polymer electrolytes for lithium-based batteries: advances and prospects. Chem2019; 5: 2326–2352. doi: https://doi.org/10.1016/j.chempr.2019.05.009
100.
MarkevichESalitraGAurbachD. Fluoroethylene carbonate as an important component for the formation of an effective solid electrolyte interphase on anodes and cathodes for advanced Li-ion batteries. ACS Energy Lett2017; 2: 1337–1345.
101.
LiR, et al.Constructing highly stable solid electrolyte interphase for Si@graphene anodes by coupling 2-isocyanatoethyl methacrylate and fluoroethylene carbonate. J Power Sources2023; 554: 232337.
102.
LiZ, et al.Nonflammable quasi-solid electrolyte for energy-dense and long-cycling lithium metal batteries with high-voltage Ni-rich layered cathodes. Energy Storage Mater2022; 47: 542–550.
103.
SunM, et al.Fast Li+ transport pathways of quasi-solid-state electrolyte constructed by 3D MOF composite nanofibrous network for dendrite-free lithium metal battery. Mater Today Energy2022; 29. doi: https://doi.org/10.1016/j.mtener.2022.101117
104.
ZhuT, et al.Constructing flame-retardant gel polymer electrolytes via multiscale free radical annihilating agents for Ni-rich lithium batteries. Energy Storage Mater2022; 50: 495–504.
