Jasminum flexile flower absolute from the south of India and the corresponding vacuum, headspace (VHS) sample of the absolute were analyzed using GC and GC-MS. Three other commercially available Indian jasmine absolutes from the species: J. sambac, J. officinale subsp. grandiflorum, and J. auriculatum and the respective VHS samples were used for comparison purposes. One hundred and twenty-one compounds were characterized in J. flexile flower absolute, with methyl linolate, benzyl salicylate, benzyl benzoate, (2E,6E)-farnesol, and benzyl acetate as the main constituents. A detailed olfactory evaluation was also performed.
KroemerK. (2008) Senses - India: an expedition into the world of senses, Symrise GmbH & Co. KG, Holzminden, No. II, 6–45.
2.
KennedyRR, ThangarajT. (2000) Exploitation of perfume potentials of certain non-conventional flower species of South India. Journal of Medicinal and Aromatic Plant Sciences, 22, 525–527.
3.
NavesYR. (1974) Technologie et Chimie des Parfums Naturels; Essences Concrètes, Resinoides, Huiles et Pommades aux Fleurs. Masson, Paris (France), 160–175.
NigamMC, MisraLN. (1980) Chemistry of jasmine oil: a review. Current Research on Medicinal and Aromatic Plants, 2, 37–44;
6.
van der GenA. (1972) Corps olfactifs à l'odeur de jasmin. Parfums, Cosmetiques, Savons de France, 2, 356–370.
7.
JirovetzL, BuchbauerG, SchweigerT, DenkovaZ, SlavchevA, StoyanovaA, SchmidtE, GeisslerM. (2007) Chemical composition, olfactory evaluation and antimicrobial activities of Jasminum grandiflorum L. absolute from India. Natural Product Communications, 2, 407–412;
8.
DemoleEP. (1982) The fragrance of Jasmine. In Fragrance Chemistry - The Science of the Sense of Smell, TheimerET. (Ed), Academic Press, New York, 249–396; and references cited therein.
9.
EdrisAE, ChizzolaR, FranzC. (2008) Isolation and characterization of the volatile aroma compounds from the concrete headspace and the absolute of Jasminum sambac (L.) Ait. (Oleaceae) flowers grown in Egypt. European Food Research and Technology, 226, 621–626;
10.
KaiserR. (1988) New volatile constituents of Jasminum sambac (L.) Aiton. In: Flavors and Fragrances: A World Perspective. LawrenceBM, MookherjeeBD, WillisBJ (Eds.), Elsevier, Amsterdam, 669–684; and references cited therein.
11.
B.F. (1994) Jasmine, the king of flowers. Parfums, Cosmetiques, Aromes, 119, 58–64;
12.
LawrenceBM. (1988) Progress in essential oils - Jasmine extracts. Perfumer and Flavorist, 13, 69–76; and references cited therein.
13.
JoulainD, LaurentR. (1995) The absolute from flowers of Jasminum auriculatum Vahl from India. Flavour and Fragrance Journal, 10, 193–197.
14.
RamachandriahOS, ReddyPN, GautamaA, AzeemoddinG, RamayyaDA, RaoSDT. (1984) Studies in Indian essential oil: V. oils from Jasmine. Indian Perfumer, 28, 24–27;
15.
BhattacharjeeSK, DivakarNG. (1984) Growth, flowering and essential oil content of different species of Jasminum as affected by Ethrel. Indian Journal of Horticulture, 41, 131–136;
16.
MoreTA. (1980) Extraction of essential oil from Jasminum. Science and Culture, 46, 428–429.
17.
JoulainD. (1986) Study of the fragrance given off by certain spring time flowers. In Progress in Essential Oil Research. BrunkeEJ. (Ed). De Gruyter, Berlin, 57–67.
18.
SurburgH, PantenJ. (2006) Common Fragrance and Flavor Material, 5th ed., Wiley-VCH, Weinheim, 178–181;
19.
SellC. (2006) Perfumery materials of natural origin. In The chemistry of fragrances, 2nd ed. SellC. (Ed). Royal Society of Chemistry, Cambridge, 33–43.
20.
KönigWA, JoulainD, HochmuthDH. (2004) GC/MS Library: terpenoids and related constituents of essential oils. MassFinder3.
21.
RaoYR, RoutPK (2003) Geographical location and harvest time dependent variation in the composition of essential oils of Jasminum sambac (L.) Aiton. Journal of Essential Oil Research, 15, 398–401.
22.
RaoYR, RoutPK (2002) Composition of the essential oil and headspace of flowers of Jasminum sambac (Linn) Ait. Indian Perfumer, 46, 49–53.
23.
MalekSN, ZakariaZ. (1995) The chemical composition of Malaysian jasmine flower absolute Jasminum multiflorum L. ACGC Chemical Research Communications, 3, 15–20.
24.
BuckLB. (2008) Unraveling smell. In The Harvey Lectures: Series 101, 2005-2006. Harvey Society (Ed). Wiley, New York, 117–134;
25.
PeterlinZ, LiY, SunG, ShahR, FiresteinS, RyanK. (2008) The importance of odorant conformation to the binding and activation of a representative olfactory receptor. Chemistry and Biology, 15, 1317–1327.
26.
For reviews see: (a) JoulainD. (1993) Cryogenic vacuum trapping of scents from temperate and tropical flowers. In Bioactive Volatile Compounds from Plants. ACS Symposium Series Vol. 525, TeranishiR, ButteryRG, SugisawaH. (Eds). American Chemical Society, Washington DC, 187–204;
27.
SurburgH, GüntertM, HarderH. (1993) Volatile compounds from flowers: analytical and olfactory aspects. In Bioactive Volatile Compounds from Plants. ACS Symposium Series Vol. 525, TeranishiR, ButteryRG, SugisawaH. (Eds). American Chemical Society, Washington DC, 168–186;
28.
SurburgH, GüntertM, HarderH. (1993) Investigation of volatiles from flowers; analytical and olfactory aspects. In Recent Developments in Flavor and Fragrance Chemistry: Proceedings of the 3rd International Haarmann & Reimer Symposium. HoppR, MoriK. (Eds). VCH, Weinheim, Germany, 103–121.
29.
For reviews see: (a) WerkhoffP, GüntertM, KrammerG, SommerH, KaulenJ. (1998) Vacuum headspace method in aroma research: flavor chemistry of yellow passion fruits. Journal of Agricultural and Food Chemistry, 46, 1076–1093;
30.
GüntertM, KrammerG, SommerH, WerkhoffP. (1998). The importance of the vacuum headspace method for the analysis of fruit flavors. In: Flavor Analysis - Developments in Isolation and Characterization. ACS Symposium Series Vol. 705, MussinanCJ, MorelloMJ. (Eds). American Chemical Society, Washington DC, 38–60.
31.
ValetteL, FernandezX, PoulainS, Lizzani-CuvelierL, LoiseauAM. (2006) Chemical composition of the volatile extracts from Brassica oleracea L. var. botrytis ‘Romanesco’ cauliflower seeds. Flavour and Fragrance Journal, 21, 107–110;
32.
JoulainD, CasazzaA, LaurentR, PortierD, GuillamonN, PandyaR, LeM, ViljoenA. (2004) Volatile flavor constituents of fruits from Southern Africa: mobola plum (Parinari curatellifolia). Journal of Agricultural and Food Chemistry, 52, 2322–2325;
33.
DuL, LykkesfeldtJ, OlsenCE, HalkierBA. (1995) Involvement of cytochrome P450 in oxime production in glucosinolate biosynthesis as demonstrated by an in vitro microsomal enzyme system isolated from jasmonic acid-induced seedlings of Sinapis alba L. Proceedings of the National Academy of Sciences of the United States of America, 92, 12505–12509;
34.
KaiserR. (1991) New volatile constituents of the flower concrete of Michelia champaca L. Journal of Essential Oil Research, 3, 129–146;
35.
MahadevanS. (1973) Role of oximes in nitrogen metabolism in plants. Annual Review of Plant Physiology, 24, 69–88.
36.
RagusoRA, HenzelC, BuchmannSL, NabhanGP. (2003) Trumpet flowers of the Sonoran desert: floral biology of Peniocereus cacti and sacred Datura. International Journal of Plant Sciences, 164, 877–892;
37.
KaiserR. (1993) The Scent of Orchids, Elsevier Science Publishers, Amsterdam.
38.
LawrenceBM. (2009) A preliminary report on the world production of some selected essential oils and countries. Perfumer and Flavorist, 34, 38–44.
39.
JoulainD. (2008) Flower scents from the Pacific. Chemistry and Biodiversity, 5, 896–909.
40.
For a recent example in the literature see: SadhuSK, KhanMD, OhtsukiT, IshibashiM. (2007) Secoiridoid components from Jasminum grandiflorum. Phytochemistry68, 1718–1721.
41.
OhloffG. (1990) Riechstoffe und Geruchssinn: die molekulare Welt der Düfte, spinger Verlag, Berlin, 149–152.
We thank the Singapore Herbarium (SING) and its staff especially Dr HughesM and Dr TanBC, Singapore Botanic Gardens, Singapore for clarification of the taxonomy of J. officinale subsp. grandiflorum.
