The chemical constituents of the root of Ligularia duciformis, collected in Yunnan Province of China, was studied and two new oplopane-type sesquiterpenoids were isolated, whose structures were determined on the basis of spectroscopic evidence. Quite recently, oplopane-type compounds were found in Ligularia narynensis, and this is the second example to isolate oplopane-type sesquiterpenoids from Ligularia plants.
HanaiR, GongX, ToriM, KondoS, OtoseK, OkamotoY, NishihamaT, MurotaA, ShenY, WuS, KurodaC. (2005) Chemical and genetic study of Ligularia tongolensis, Ligularia cymbulifera, and Ligularia atroviolaceae in the Hengduan mountains of China. Bulletin of Chemical Society of Japan, 78, 1302–1308.
2.
NaganoH, IwazakiY, GongX, ShenY, KurodaC, HanaiR. (2006) Chemical and genetic differenciation of Ligularia pleurocaulis in Northwestern Yunnan and Southwestern Sichuan Provinces of China. Bulletin of Chemical Society of Japan, 79, 300–304.
3.
ToriM, HondaK, NakamizoH, OkamotoY, SakaokuM, TakaokaS, GongX, ShenY, KurodaC, HanaiR. (2006) Chemical constituents of Ligularia virgaurea and its diversity in southwestern Sichuan of China. Tetrahedron, 62, 4988–4996.
4.
(a) GaoK, JiaZJ, WangWS. (1997) Five coniferyl alcohol derivatives from Ligularia duciformis.Chemical Research in Chinese Universities, 13, 382–385
5.
(b) GaoK, JiaZJ. (1999) Two new sesquiterpenes from Ligularia duciformis.Chemical Research in Chinese Universities, 15, 70–72
6.
(c) GaoK, LiY, JiaZJ. (1999) Sesquiterpenes from the roots of Ligularia duciformis.Journal of Chinese Chemical Society, 46, 619–622
7.
(d) GaoX, LinCJ, XieWD, ShenT, JiaZJ. (2006) New oplopane-type sesquiterpenes from Ligularia narynensis.Helvetica Chimica Acta, 89, 1387–1394.
8.
The numbering followed the Dictionary of Terpenoids, ConnollyJD and HillRA. (1991) Chapman and Hall, London, UK.
ShibuyaH, TakedaY, ZhangRS, TongEX, KitagawaI. (1992) Indonesian Medicinal Plants. III. On the Constituents of the Bark of Fagara rhetza (Rutaceae). (1): Alkaloids, Phenylpropanoids, and Acid Amide. Chemical & Pharmaceutical Bulletin, 40, 2325–2330.
11.
HayashiK. (1989) Oplopane sesquiterpenoids from Petasites palmatus.Phytochemistry, 28, 3373–3376.
12.
(a) BohlmannF, SuwitaA. (1976) Über die Inhaltsstoffe von Senecio abrotanifolius L. Chemische Bererichte, 109, 2014–2020
13.
(b) BohlmannF, MahantaPK. (1979) Neue bisabolen- und andere sesquiterpen-derivate aus Senecio coccineiflorus und S. ovirensis. Phytochemistry, 18, 678–680
14.
(c) Joseph-NathanP, VillagómezJR, RománLU, HernándezJD. (1989) An oplopane from Senecio mexicanus.Phytochemistry, 28, 1207–1209.
15.
BohlmannF, GuptaRK, JakupovicJ, KingRM, RobinsonH. (1982) Four oplopane and bisabolone derivatives from Rugelia nudicaulis.Phytochemistry, 21, 1665–1668.
16.
YaoitaY, KamazawaH, KikuchiM. (1999) Structures of new oplopane-type sesquiterpenoids from the flower buds of Tussilago farfara L. Chemical & Pharmaceutical Bulletin, 47, 705–707.
17.
ArciniegasA, Pérez-CastorenaAL, ReyesS, ContrerasJL, Romo de VivarA. (2003) New oplopane and eremophilane derivatives from Robinsonecio gerberifolius.Journal of Natural Products, 66, 225–229.