Mechanical and tribological behaviour of three-dimensional printed almond shell particles reinforced polylactic acid bio-composites

Abstract

Recently, composite filament development for three-dimensional printing has emerged and is used for numerous applications. The present research work develops neat polylactic acid and Almond Shell Particles reinforced polylactic acid bio-composites for three-dimensional printing and investigates the effects of printing orientation, including 0°, 45° and 90° orientation, on the tribological and mechanical behaviours of three-dimensional printed materials. The novel almond shell particles reinforced polylactic acid filaments are extruded by the filament extrusion method with the presence of 10% almond shell particles in the polylactic acid matrix, and the samples are three-dimensional printed by the fused filament fabrication technique. Mechanical characteristics such as tensile, flexural, compressive strength, and shore hardness are evaluated with respect to various three-dimensional printing orientations. The surface quality of the three-dimensional printed polylactic acid composite samples is analysed with respect to length and diameter deviation. Length accuracy of the 90° oriented polylactic acid and almond shell particles reinforced polylactic acid bio-composite samples exploits a better accuracy of 99.12% and 98.81%, respectively. It is shown that adding almond shell particles to the polylactic acid matrix decreases the flexural and tensile strength. Among the printing orientations, 0° flat samples result in the maximum tensile strength of 36 and 28 MPa for the neat polylactic acid and almond shell particles reinforced polylactic acid composites, respectively. The lowest contact angle of 54° is observed on the almond shell particles reinforced polylactic acid bio-composites three-dimensional printed with a 90° orientation. The highest contact angle value of 94° is observed on the neat polylactic acid three-dimensional printed with a 0° printing orientation. A tribological study is carried out under dry conditions on the pin-on-disc tribometer by varying the sliding speed (1, 2, and 3 m/s) and load (10, 20, and 30 N). The result shows that the lowest coefficient of friction of 0.22 is achieved for the almond shell particles reinforced polylactic acid bio-composite samples with a 0° printing orientation under a sliding load of 10 N. These kinds of newly developed compostable materials can be used for developing disposable orthotic foot appliances.