Treatment of refractory organics in biologically treated landfill leachate by a zero valent iron enhanced Peroxone process: Degradation efficiency and mechanism study

Abstract

A zero valent iron (ZVI) enhanced Peroxone process (ZVI/Peroxone) was used to treat biologically treated landfill leachate (BTL). The treatment efficiency of the ZVI/Peroxone process was compared to single (ZVI, O₃ and H₂O₂) and dual (ZVI/H₂O₂, Fe⁰/O₃ and Peroxone) processes. The results showed that ZVI can greatly enhance the treatment capability of the Peroxone process, and the color number (CN), absorbance at 254 nm (UV₂₅₄), and total organic carbon (TOC) removal efficiencies were 98.82, 84.30 and 66.38%, respectively. In the ZVI/Peroxone process, higher O₃ and ZVI dosages improved organics removal, and H₂O₂ could promote organics removal within a certain dosage range. However, too much H₂O₂ decreased treatment efficiency. The best treatment performance by the ZVI/Peroxone process was obtained under acidic conditions. The three-dimensional excitation and emission matrix analysis showed that BTL mainly contained two fluorescent substances, which were fulvic-like substances in the ultraviolet region (Ex/Em = 235–255 nm/410–450 nm) and fulvic-like substances in the visible light region (Ex/Em = 310–360 nm/370–450 nm). Fluorescent substances could be substantially degraded by the ZVI/Peroxone process during the early stages of the reaction. An analysis of ZVI morphology and element valency changes showed that the micro Fe⁰ particles used in this study remained highly reactive during the process. The ZVI enhanced the homogenous Fenton, heterogeneous Fenton, and coagulation-flocculation effects during the Peroxone process.