In this study, we developed hexagon silver nanoparticles (AgNPs) prepared by the polyol method in ethylene glycol media using aminopropyltrimethoxysilane (APTMS) as a capping agent for the first time. The presence of the primary amine group makes APTMS a great candidate as a capping agent for the synthesis of silver nanostructures, but it has not been used for this purpose until now. The synthesized silver nanostructures were characterized by transmission electron microscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry and ultraviolet-visible spectroscopy. The molar ratio of APTMS to AgNO3 varied from 0.5 to 6.8, which resulted in an average diameter of the obtained nanoparticles from 50 to 100 nm. The optimum morphology of hexagonally shaped AgNPs was obtained at a molar ratio of 2.2. The prepared AgNPs were evaluated for their antibacterial and antifungal properties. Antimicrobial tests showed that a cotton textile coated with colloidal amino functionalized AgNPs has excellent antimicrobial properties as an inhibitor of growth against the gram-positive bacteria Staphylococcus aureus, gram-negative bacteria, Escherichia coli and fungus Candida albicans, and therefore showing potential for real applications.
DangHFawcettDPoinernGEJ. Biogenic synthesis of silver nanoparticles from waste banana plant stems and their antibacterial activity against Escherichia coli and Staphylococcus Epidermis. Int J Res Med Sci2017; 5: 3769–3775.
2.
KumarBSmitaKCumbalL, et al.Green synthesis of silver nanoparticles using Andean blackberry fruit extract. Saudi J Biol Sci2017; 24: 45–50.
3.
HaseebMTHussainMAAbbasK, et al.Linseed hydrogel-mediated green synthesis of silver nanoparticles for antimicrobial and wound-dressing applications. Int J Nanomed2017; 12: 2845–2855.
4.
ChenCWangLYuH, et al.Study on the growth mechanism of silver nanorods in the nanowire-seeding polyol process. Mater Chem Phys2008; 107: 13–17.
5.
SimoncicBTomsicB. Structures of novel antimicrobial agents for textiles - a review. Text Res J2010; 80: 1721–1737.
6.
WileyBSunYMayersB, et al.Shape-controlled synthesis of metal nanostructures: the case of silver. Chem A Eur J2005; 11: 454–463.
7.
PrietoPNistorVNounehK, et al.XPS study of silver, nickel and bimetallic silver– nickel nanoparticles prepared by seed-mediated growth. Appl Surf Sci2012; 258: 8807–8813.
8.
ZhuJJKanXCWanJG, et al.High-yield synthesis of uniform ag nanowires with high aspect ratios by introducing the long-chain PVP in an improved polyol process. J Nanomater. Epub ahead of print 1 January 2011. DOI: 10.1155/2011/982547.
9.
AmirjaniAMarashiPFatmehsariDH. Effect of AgNO3 addition rate on aspect ratio of CuCl2–mediated synthesized silver nanowires using response surface methodology. Colloid Surf A Physicochem Eng Aspect2014; 444: 33–39.
10.
ChoKHParkJEOsakaT, et al.The study of antimicrobial activity and preservative effects of nanosilver ingredient. Electrochimica Acta2005; 51: 956–960.
11.
ZhangWQiaoXChenJ. Synthesis of nanosilver colloidal particles in water/oil microemulsion. Colloid Surf A Physicochem Eng Aspect2017; 299: 22–28.
12.
WileyBSunYXiaY. Synthesis of silver nanostructures with controlled shapes and properties. Acc Chem Res2007; 40: 1067–1076.
13.
ChenCWangLJiangG, et al.Study on the synthesis of silver nanowires with adjustable diameters through the polyol process. Nanotechnology2006; 17: 3933–3938.
14.
NishinoJKannoY. An influence of concentration of polyvinylpyrrolidone on the morphology of silver metal formed from AgNO3 aqueous solution. J Nanomater. Epub ahead of print 1 January 2008. DOI: 10.1155/2008/592838.
15.
ZhaoTSunRYuS, et al.Size-controlled preparation of silver nanoparticles by a modified polyol method. Colloid Surf A Physicochem Eng Aspect2010; 366: 197–202.
16.
AltinsoyBDSeker-KaratoprakGOcsoyI. Extracellular directed ag NPs formation and investigation of their antimicrobial and cytotoxic properties. Saudi Pharm J2019; 27: 9–16.
17.
MartinTPKooiSEChangSH, et al.Initiated chemical vapor deposition of antimicrobial polymer coatings. Biomaterials2007; 28: 909–915.
18.
QuangDVSarawadePBHilongaA, et al.Preparation of amino functionalized silica micro beads by dry method for supporting silver nanoparticles with antibacterial properties. Colloid Surf A Physicochem Eng Aspect2011; 389: 118–126.
JeonHJYiSCOhSG. Preparation and antibacterial effects of Ag–SiO2 thin films by sol–gel method. Biomaterials2003; 24: 4921–4928.
21.
XiuZMZhangQbPuppalaHL, et al.Particle-specific antibacterial activity of silver nanoparticles. Nano Lett2012; 12: 4271−4275.
22.
ChenCWangLJiangG, et al.The influence of seeding conditions and shielding gas atmosphere on the synthesis of silver nanowires through the polyol process. Nanotechnology2006; 17: 466–474.
23.
WileyBJImSHLiZH, et al.Maneuvering the surface plasmon resonance of silver nanostructures through shape-controlled synthesis. J Phys Chem B2006; 110: 15666–15675.
24.
DermenciKBGencBEbinB, et al.Photocatalytic studies of Ag/ZnO nanocomposite particles produced via ultrasonic spray pyrolysis method. J Alloy Compound2014; 586: 267–273.
25.
AbbasiEMilaniMAvalSF, et al.Silver nanoparticles: synthesis methods, bio-applications and properties. Crit Rev Microbiol2016; 42: 173–180.
26.
IravaniSKorbekandiHMirmohammadi, et al.Synthesis of silver nanoparticles: chemical, physical and biological methods. Res Pharm Sci2014; 9: 385–406.
27.
XueCHChenJYinW, et al.Superhydrophobic conductive textiles with antibacterial property by coating fibers with silver nanoparticles. Appl Surf Sci2012; 258: 2468–2472.
28.
AnandKKaviyarasuKMuniyasamyS, et al.Bio-synthesis of silver nanoparticles using agroforestry residue and their catalytic degradation for sustainable waste management. J Cluster Sci2017; 28: 2279–2291.
29.
ASTM E2149-13a. Standard test method for determining the antimicrobial activity of antimicrobial agents under dynamic contact conditions, ASTM International, 2013.
30.
ASTM E2149-10a. Standard test method for determining the antimicrobial activity of immobilized antimicrobial agents under dynamic contact conditions, ASTM International, 2010.
31.
Fras ZemljicLSauperlOKrezeT, et al.Characterization of regenerated cellulose fibers antimicrobial functionalized by chitosan. Text Res J2012; 83: 185–196.
32.
FanQCuiHFuaC. The effect of functionalized silver on rheological and electrical properties of conductive adhesives. ECS Trans2011; 34: 811–816.
33.
MaMZhangYYuW, et al.Preparation and characterization of magnetite nanoparticles coated by amino silane. Colloids Surfaces A Physicochem Eng Aspect2003; 212: 219–226.
34.
MasoumiAGhaemyMBakhtAN. Removal of metal ions from water using poly(MMA-co-MA)/ modified-Fe3O4 magnetic nanocomposite: isotherm and kinetic study. Ind Eng Chem Res2014; 53: 8188−8197.
35.
LeeHHChouKSShihZW. Effect of nano-sized silver particles on the resistivity of polymeric conductive adhesives. Int J Adhesion Adhesive2005; 25: 437–441.
36.
YouCHanCWangX, et al.The progress of silver nanoparticles in the antibacterial mechanism, clinical application and cytotoxicity. Mol Biol Rep2012; 39: 9193–9201.
