A TiO2/ZnO composite film which served as the bind-free anode for lithium-ion battery was rapidly constructed on Ti foil by the one-step plasma electrolytic oxidation process. The fabricated TiO2-based transition metal oxide composites took advantage of the high theoretical capacity of ZnO and the good structural stability of TiO2, showing a high specific capacity (706.2 mAh g−1 over 400 cycles at 0.1 A g−1) and a good rate capability (capacity reversible after 2.0 A g−1). When the scan rate gradually elevated from 0.2 to 1.0 mV s−1, the pseudocapacitance contribution increased from 63.9% to 81.2%. Besides, the hole-containing morphology of the film guaranteed efficient diffusion and excellent dynamic characteristics for Li + . The whole film preparation process was accompanied by a facile in-liquid plasma discharge with an average electron temperature of 3519 K. This high-efficiency and low-cost approach extends the practical territory of transition metal oxide anodes.
CrosbyJ.Development of a flexible printed paper-based battery [dissertation]. Kalamazoo (MI): Western Michigan University; 2020.
3.
WangH, YaoC, NieH, Recent progress in carbonyl-based organic polymers as promising electrode materials for lithium-ion batteries (LIBs). J Mater Chem A. 2020;8:11906–11922.
4.
NagalakshmiM, KalaiselviN.Mesoporous dominant cashewnut sheath derived bio-carbon anode for LIBs and SIBs. Electrochim Acta. 2019;304:175–183.
5.
WuC, HuangH, LuW, Mg doped Li–LiB alloy with in situ formed lithiophilic LiB skeleton for lithium metal batteries. Adv Sci. 2020;7:1902643.
6.
ZhangQ, CuiX, HaoS, Chain engineering of carbonyl polymers for sustainable lithium-ion batteries. Mater Today. 2021;50:170–198.
7.
XiangJ, WeiY, ZhongY, Building practical high-voltage cathode materials for lithium-ion batteries. Adv Mater. 2022. doi:10.1002/adma.202200912
8.
NoemiD.Strategies to improve the electrochemical performance of transition metal compounds as anode materials for Li-ion batteries [dissertation]. El Paso (TX): University of Texas at El Paso; 2019.
9.
LiP, LiuY, LiuJ, Facile synthesis of ZnO/mesoporous carbon nanocomposites as high-performance anode for lithium-ion battery. Chem Eng J. 2015;271:173–179.
10.
HawkinsBE, TurneyDE, MessingerRJ, Electroactive ZnO: mechanisms, conductivity, and advances in Zn alkaline battery cycling. Adv Energy Mater. 2022;12:2103294.
11.
PanQ, QinL, LiuJ, Flower-like ZnO-NiO-C films with high reversible capacity and rate capability for lithium-ion batteries. Electrochim Acta. 2010;55:5780–5785.
12.
YuanG, WangG, WangH, Synthesis and electrochemical investigation of radial ZnO microparticles as anode materials for lithium-ion batteries. Ionics. 2015;21:365–371.
13.
BuiVKH, PhamTN, HurJ, Review of ZnO binary and ternary composite anodes for lithium-ion batteries. Nanomaterials. 2021;11:2001.
14.
KushimaA, LiuXH, ZhuG, Leapfrog cracking and nanoamorphization of ZnO nanowires during in situ electrochemical lithiation. Nano Lett. 2011;11:4535–4541.
15.
FuQ, AzmiR, SarapulovaA, Electrochemical and structural investigations of different polymorphs of TiO2 in magnesium and hybrid lithium/magnesium batteries. Electrochim Acta. 2018;277:20–29.
16.
BergerO.Understanding the fundamentals of TiO2 surfaces. part I. The influence of defect states on the correlation between crystallographic structure, electronic structure and physical properties of single-crystal surfaces. Surf Eng. 2022;38:91–149.
17.
ChenL, QuY, WeiK, Fabrication and characterization of microarc oxidation films on Ti-39Nb-6Zr alloy at different voltages in KOH electrolyte. J Alloys Compd. 2017;725:1158–1165.
18.
SunM, WuJ, LuP, Sphere-like MoS2 and porous TiO2 composite film on Ti foil as lithium-ion battery anode synthesized by plasma electrolytic oxidation and magnetron sputtering. J Alloys Compd. 2022;892:162075.
19.
DuanYF, LiuJW, WangP.Effect of In2(SO4)3 on characteristics of Al-Li alloy MAO coating. Surf Eng. 2022;38:440–447.
20.
WuJ, LuP, DongL, Combination of plasma electrolytic oxidation and pulsed laser deposition for preparation of corrosion-resisting composite film on zirconium alloys. Mater Lett. 2020;262:127080.
21.
WangZ, ChenJ, SunS, Plasma-enabled synthesis and modification of advanced materials for electrochemical energy storage. Energy Storage Mater. 2022;50:161–185.
22.
AliofkhazraeiM, MacdonaldDD, MatykinaE, Review of plasma electrolytic oxidation of titanium substrates: mechanism, properties, applications and limitations. Appl Surf Sci Adv. 2021;5:100121.
23.
WuJ, ZhangY, LiuR, Anti-corrosion layer prepared by plasma electrolytic carbonitriding on pure aluminum. Appl. Surf. Sci. 2015;347:673–678.
DehnaviV, BinnsWJ, NoëlJJ, Growth behaviour of low-energy plasma electrolytic oxidation coatings on a magnesium alloy. J Magnes Alloys. 2018;6:229–237.
26.
LuP, WuJ, ZhaoH, One-step plasma electrolytic oxidation for TiO2/SnO2 film as LIB anode. Surf Eng. 2021;37:918–925.
27.
WagemakerM, KearleyGJ, Van WellAA, Multiple Li positions inside oxygen octahedra in lithiated TiO2 anatase. J Am Chem Soc. 2003;125:840–848.
28.
KavanL, RathouskýJ, GrätzelM, Surfactant-templated TiO2 (anatase): characteristic features of lithium insertion electrochemistry in organized nanostructures. J Phys Chem B. 2000;104:12012–12020.
29.
MadianM, EychmüllerA, GiebelerL.Current advances in TiO2-based nanostructure electrodes for high performance lithium-ion batteries. Batteries. 2018;4(7).
WuJ, HeX, LiG, Rapid construction of TiO2/SiO2 composite film on Ti foil as lithium-ion battery anode by plasma discharge in solution. Appl Phys Lett. 2019;114:043903.
32.
ZhangJ, XuQ, LiM, UV Raman spectroscopic study on TiO2. II. effect of nanoparticle size on the outer/inner phase transformations. J Phys Chem C. 2009;113:1698–1704.
WahabR, AnsariSG, KimYS, Low temperature solution synthesis and characterization of ZnO nano-flowers. Mater Res Bull. 2007;42:1640–1648.
35.
ZhouQ, ChenJ, JinB, Modification of ZIF-8 on bacterial cellulose for an efficient selective capture of U(VI). Cellulose. 2021;28:5241–5256.
36.
FuZ, HuangF, ZhangY, The electrochemical reaction of zinc oxide thin films with lithium. J Electrochem. Soc. 2003;150:A714.
37.
HuangXH, XiaXH, YuanYF, Porous ZnO nanosheets grown on copper substrates as anodes for lithium-ion batteries. Electrochim Acta. 2011;56:4960–4965.
38.
LiuJ, LiY, HuangX, Layered double hydroxide nano- and microstructures grown directly on metal substrates and their calcined products for application as Li-ion battery electrodes. Adv Funct Mater. 2008;18:1448–1458.
39.
HuangXH, GuoRQ, WuJB, Mesoporous ZnO nanosheets for lithium-ion batteries. Mater Lett. 2014;122:82–85.
40.
ShenX, MuD, ChenS, Enhanced electrochemical performance of ZnO-loaded/porous carbon composite as anode materials for lithium ion batteries. ACS Appl Mater Interfaces. 2013;5:3118–3125.
41.
ZhangCQ, TuJP, YuanYF, Electrochemical performances of Ni-coated ZnO as an anode material for lithium-ion batteries. J Electrochem Soc. 2007;154:A65.
42.
AugustynV, ComeJ, LoweMA, High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat Mater. 2013;12:518–522.
43.
LiuD, YangL, ChenZ, Ultra-stable Sb confined into N-doped carbon fibers anodes for high-performance potassium-ion batteries. Sci Bull. 2020;65:1003–1012.
44.
LübkeM, ShinJ, MarchandP, Highly pseudocapacitive Nb-doped TiO2 high power anodes for lithium-ion batteries. J Mater Chem A. 2015;3:22908–22914.
45.
WangJ, PolleuxJ, LimJ, Pseudocapacitive contributions to electrochemical energy storage in TiO2 (anatase) nanoparticles. J Phys Chem C. 2007;111:14925–14931.
46.
QiuJ, ZhangP, LingM, Photocatalytic synthesis of TiO2 and reduced graphene oxide nanocomposite for lithium ion battery. ACS Appl Mater Interfaces. 2012;4:3636–3642.
47.
LeeG, KimS, KimS, Sio2/TiO2 composite film for high capacity and excellent cycling stability in lithium-ion battery anodes. Adv Funct Mater. 2017;27:1703538.
48.
WangX, HaoH, LiuJ, A novel method for preparation of macroposous lithium nickel manganese oxygen as cathode material for lithium-ion batteries. Electrochim Acta. 2011;56:4065–4069.
