Abstract
The synthesis and single crystal X-ray studies of bis(trimethylsilylmethyl) telluriumdiiodide was studied through an insertion route with quantitative yield. This molecule was characterized with the help of 1H NMR, elemental analysis and single-crystal X-ray studies. The new crystalline molecule provides a supramolecular synthon in crystal lattices of tellurium(IV) diiodide showing 2d synthons associated with the help of C-H - - - I interactions.
Get full access to this article
View all access options for this article.
References
1.
Wöhler
F.
Ann Chem 35 (1840 ), 111 .
2.
(a)
Irfan
M.
Rehman
R.
Razall
M.R.
Rehman
S.-U.
–Rehman
A.-U.
Iqbal
M.A.
Rev Inorg Chem 40 (2020 ), 193 –232 ; (b) C.W. Nogueira, G. Zeni and J.B.T. Rocha, Chem Rev 104 (2004), 6255–6285.
3.
Engman
L.
Acc Chem Res 16 (1985 ), 274 –279 .
4.
Singh
H.B.
Sudha
N.
Polyhedron 15 (1996 ), 745 –763 .
5.
(a)
Chauhan
A.K.S.
Anamika
Kumar
A.
Singh
P.
Srivastava
R.C.
Butcher
R.J.
Beckmann
J.
Duthie
A.
Organomet Chem 691 (2006 ), 1954 –1964 ; (b) P. Singh, S. Sharma, H.B. Singh and R.J. Butcher, Proc Natl Acad Sci India A 84 (2014), 269–280; (c) P. Singh, H.B. Singh and R. J. Butcher, Acta Cryst E70 (2014), 911–912; (d) P. Singh, H.B. Singh and R.J. Butcher, Acta Cryst E74 (2018), 151–1154.
6.
(a)
Manna
D.
Roy
G.
Mugesh
G.
Acc Chem Res 46 (2013 ), 2706 –2715 ; (b) P. Singh, H.B. Singh and R.J. Butcher, J Organomet Chem 876 (2018), 1–9; (c) V.P. Singh, P. Singh, H.B. Singh and R.J. Butcher, Tetrahedron Lett 53 (2012), 4591–4594.
7.
(a)
Mousavi
M.
Mittal
U.
Ghasemian
M. B.
Baharfar
M.
Tang
J.
Yao
Y.
Merhebi
S.
Zhang
C.
Sharma
N.
Zadeh
K. K.
Mayyas
M.
, ACS Appl Mater Interfaces 45 (2022 ), 51519 –51530 .
8.
Pietrasiak
E.
Togni
A.
, Organometallics 36 (2017 ), 3750 –3757 .
9.
Kieser
J.M.
Jones
L.O.
Uible
M.C.
Zeller
M.
Schatz
G.C.
Bart
S.C.
, Organometallics 40 (2021 ), 4104 –4109 .
10.
Han
Li-B.
Mirzaei
F.
Tanaka
M.
, Organometallics 19 (2000 ), 722 –724 .
11.
Beletskaya
I.P.
Voskoboynikov
A.Z.
Shestakova
A.K.
Schumann
H.
, J Organomet Chem 463 (1993 ), C1 –C2 .
12.
Sahoo
S.
Mobin
S.M.
Ghosh
S.
, J Organomet Chem 695 (2010 ), 945 –949 .
13.
Sinha
A.
Ravikanth
M.
, J Org Chem 88 (2023 ), 39 –48 .
14.
Chauhan
A.K.S.
Singh
P.
Kumar
A.
Srivastava
R.C.
Butcher
R.J.
Duthie
A.
, Organometallics 26 (2007 ), 1955 –1959 .
15.
Chauhan
A.K.S.
Singh
P.
Srivastava
R.C.
Duthie
A.
Voda
A.
, Dalton Trans (2008), 4023–4028.
16.
Chauhan
A.K.S.
Singh
P.
Srivastava
R.C.
Butcher
R.J.
Duthie
A.
, J Organomet Chem 695 (2010 ), 2118 –2125 .
17.
Misra
S.
Chauhan
A.K.S.
Singh
P.
Srivastava
R.C.
Duthie
A.
Butcher
R.J.
, Dalton Trans 39 (2637 ), 2637 –2643 .
18.
Singh
P.
Gupta
A.K.
Sharma
S.
Singh
H.B.
, Inorg Chim Acta 483 (2018 ), 218 –228 .
19.
Singh
P.
Shabbani
G.
Singh
A.S.
Bajaj
H.C.
Suresh
E.
, Inorg Chim Acta 484 (2019 ), 27 –32 .
20.
Singh
P.
Singh
P.
Shabbani
G.
Butcher
R.J.
, J Phys Conf Ser 1913 (2021 ), 012077 .
21.
Singh
P.
Singh
P.
Shabbani
G.
Butcher
R.J.
, J Phys Conf Ser 1913 (2021 ), 012078 .
22.
Singh
P.
Singh
P.
Butcher
R.J.
, Inorg Chim Acta 545 (2023 ), 121289 .
23.
Singh
P.
Singh
P.
Butcher
R.J.
, J Chem Crystallogr 52 (2022 ), 505 –511 .
24.
Poropudas
M.J.
Vigo
L.
Oilunkaniemi
R.
Laitinen
R.S.
Heteroat Chem , 22 (2011 ), 348 –357 .
25.
Bruker SAINT. Bruker AXS Inc., Madison (2016),.
26.
SADABS, Area Detector Absorption Correction Program; Bruker Analytical X-ray, Madison (2018),.
27.
Sheldrick
G.M.
, Acta Crystallogr C71 (2015 ), 3 .
28.
Bent
H.
, Chem. Rev 61 (1961 ), 275 .