Abstract
The reaction of N-(2-chloroethyl)benzamide and N-[3-bromopropyl]phthalimide with ArTe- Na+ generated in situ by borohydride reduction of Ar2Te 2, has resulted in N-[2-(4-methoxyphenyltelluro)ethyl] benzamide (L1) and N-[2-(4-methoxyphenyl telluro)propyl] phthalimide (L2) respectively, which are potentially (Te, N)-type ligands. Their NMR (1H and 13C) spectra are characteristic and single crystal structures are solved. The Te-C(alkyl) distance [2.140(8)/2.151(4) Å] is longer than Te-C(aryl) distance [2.107(8)/2.128(5) Å].
Keywords
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