Abstract
With a catalytic amount of 1-iodopropane and a stoichiometric oxidant m-chloroperbenzoic acid, the oxidative spirocyclisation of 4-(2-carboxyethyl)phenols proceeded smoothly, providing the corresponding spirodienones in good yields. In this protocol, 1-iodopropane was first oxidised to hypoiodous acid, which then facilitated the spirocyclisation of the phenols.
Keywords
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