Abstract
The first crystalline TPPS complex [Zn(en)TPPS][Zn(en)3] (where en is ethylenediamine and TPPS is tetraphenylporphyrin tetrasulfonic acid) has been synthesised via a solvothermal reaction and structurally characterised by a single-crystal X-ray diffraction. Zn(en)TPPS][Zn(en)3 has discrete [Zn(en)TPPS]2– and [Zn(en)3]2+ moieties, which are interconnected via hydrogen bonds to form a three-dimensional supramolecular framework that possesses a large void space (1507.6 Å3) corresponding to 22.5% of the unit-cell volume. The UV-Vis spectrum and photoluminescence have also been studied in detail.
References
1.
Kadish K.M.
,
Van Caemelbecke E.
, and
Royal G.
, The porphyrin handbook , Vol. 8 , eds
Kadish K.M.
,
Smith K.M.
, and
Guilard R.
, Academic Press , San Diego , 2000 , p. 1 .
2.
Srinivasan A.
, and
Furuta H.
, Acc. Chem. Res. , 2005 , 38 , 10 .
3.
Ren T.
, Chem. Rev. , 2008 , 108 , 4185 .
4.
Faiz J.A.
,
Heitz V.
, and
Sauvage J.P.
, Chem. Soc. Rev. , 2009 , 2 , 422 .
5.
Bucher C.
,
Devillers C.H.
,
Moutet J.C.
,
Royal G.
, and
Saint-Aman E.
, Coord. Chem. Rev. , 2009 , 253 , 21 .
6.
Yin L.
,
Wu N.
,
Curtin J.C.
,
Qatanani M.
,
Szwergold N.R.
,
Reid R.A.
,
Waitt G.M.
,
Parks D.J.
,
Pearce K.H.
,
Wisely G.B.
, and
Lazar M.A.
, Science , 2007 , 318 , 1786 .
7.
Maeda K.
,
Henbest K.B.
,
Cintolesi F.
,
Kuprov I.
,
Rodgers C.T.
,
Liddell P.A.
,
Gust D.
,
Timmel C.R.
, and
Hore P.J.
, Nature , 2008 , 453 , 387 .
8.
Goldberg I.
, Chem.–Eur. J. , 2000 , 6 , 3863 .
9.
Goldberg I.
, CrystEngComm. , 2002 , 4 , 109 .
10.
Shmilovits M.
,
Diskin-Posner Y.
,
Vinodu M.
, and
Goldberg I.
, Cryst. Growth Des. , 2003 , 3 , 855 .
11.
Dastidar P.
,
Stein Z.
,
Goldberg I.
, and
Strouse C.E.
, Supramol. Chem. , 1996 , 7 , 257 .
12.
Byrn M.P.
,
Curtis C.J.
,
Hsiou Y.
,
Khan S.I.
,
Sawin P.A.
,
Terzis A.
, and
Strouse C.E.
, Comprehen. Supramol. Chem. , 1996 , 6 , 715 .
13.
Abrahams B.F.
,
Hoskins B.F.
,
Michall D.M.
, and
Robson R.
, Nature , 1994 , 369 , 727 .
14.Rigaku (2002 ), CrystalClear Version 1.35 , Rigaku Corporation .
15.Siemens (1994 ), SHELXTLTM Ver. 5 Reference Manual , Siemens Energy & Automation Inc. , Madison, Wisconsin, USA.
16.
Konarev D.V.
,
Yu Kovalevsky A.
,
Li X.
,
Neretin I.S.
,
Litvinov A.L.
,
Drichko N.V.
,
Slovokhotov Y.L.
,
Coppens P.
, and
Lyubovskaya R.N.
, Inorg. Chem. , 2002 , 41 , 3638 .
17.
Terazono Y.
,
Patrick B.O.
, and
Dolphin D.H.
, Inorg. Chem. , 2002 , 41 , 6703 .
18.
Krupitsky H.
,
Stein Z.
, and
Goldberg I.
, Z. Kristallogr. , 1995 , 210 , 665 .
19.
Smirnov V.V.
,
Woller E.K.
,
Tatman D.
, and
DiMagno S.G.
, Inorg. Chem. , 2001 , 40 , 2614 .
20.
Wu D.M.
,
Lin X.
,
Lu C.Z.
, and
Zhuang H.H.
, Chinese J. Struct. Chem. , 2001 , 20 , 409 .
21.
Jia D.X.
,
Zhang Y.
,
Dai J.
,
Zhu Q.Y.
, and
Gu X.M.
, Z. Anorg. Allg. Chem. , 2004 , 630 , 313 .
22.
Khan M.I.
,
Yohannes E.
, and
Doedens R.J.
, Inorg. Chem. , 2003 , 42 , 3125 .
23.
Xue D.
,
Yin M.
,
Fan Y.
,
Zhu A.
,
Lu H.
, and
Hou H.
, J. Coord. Chem. , 2005 , 58 , 1449 .
24.
Brylev K.A.
,
Mironov Y.V.
,
Naumov N.G.
,
Fedorov V.E.
, and
Ibers J.A.
, Inorg. Chem. , 2004 , 43 , 4833 .
25.
Gouterman M.
, The porphyrins , vol. III , ed.
Dolphin D.
, Academic Press , New York , 1978 .