Abstract
A heterobimetallic ferrocene–ruthenium complex with a conjugated vinyl (CH=CH)6 chain has been synthesised by treatment of the mononuclear complex Fc(CH=CH)C(CH3)=(CH)4=C(CH3)(CH)2C ≡ CH with [RuHCl(CO)(PPh3)3]. Its UV-Vis absorption spectrum showed an obvious redshift and its electrochemical behaviour confirmed the existence of an electronic interaction between ruthenium and ferrocene, although the organic bridging chain included such a long carbon–carbon double bond unit.
References
1.
Lang H.
, Angew. Chem. Int. Ed. Engl. , 1994 , 106 , 569 .
2.
Bunz M.I.
, Coord. Chem. Rev. , 1997 , 166 , 91 .
3.
Poul F.
, and
Lapinte C.
, Coord. Chem. Rev. , 1998 , 427 , 178 .
4.
Tour J.M.
, Chem. Rev. , 1996 , 96 , 537 .
5.
Muller M.
,
Kubel M.
, and
Mullen K.
, Chem. Eur. J. , 1998 , 4 , 2099 .
6.
Lehn J.M.
, Angew. Chem. Int. Ed. Engl. , 1988 , 27 , 89 .
7.
Tour J.M.
, Acc. Chem. Res. , 2000 , 33 , 791 .
8.
Kheradmandan S.
,
Heinze K.
,
Schmalle J.W.
, and
Berke H.
, Angew. Chem. Int. Ed. Engl. , 1999 , 38 , 2270 .
9.
Bruce M.I.
,
Costuas K.
,
Halet J.F.
,
Hall B.C.
,
Low P.J.
,
Nicholson B.K.
,
Skelton B.W.
, and
White A.H.
, J. Chem. Soc. Dalton. Trans. , 2002 , 3 , 383 .
10.
Kanis D.R.
,
Ratner M.A.
, and
Marks T.J.
, Chem. Rev. , 1994 , 94 , 195 .
11.
Bredas J.L.
,
Adant C.
,
Tackx P.
, and
Peraoons A.
, Chem. Rev. , 1994 , 94 , 24 .
12.
Xia H.P.
, and
Jia G.C.
, Organometallics , 1997 , 16 , 1 .
13.
Xia H.P.
, and
Jia G.C.
, Organometallics , 1997 , 16 , 3557 .
14.
Fox H.H.
,
Lee J.K.
,
Lee Y.P.
, and
Schrocv R.R.
, Organometalics , 1993 , 12 , 759 .
15.
Liu S.H.
,
Xia H.P.
,
Wen T.B.
,
Zhou Z.
, and
Jia G.C.
, Organometallics , 2003 , 22 , 737 .
16.
Liu S.H.
,
Chen Y.H.
,
Wan K.L.
,
Wen T.B.
,
Zhou Z.Y.
, and
Lo M.F.
, Organometallics , 2002 , 21 , 4984 .
17.
Liu S.H.
,
Hu Q.Y.
,
Xue P.
, and
Wen T.B.
, Organometallic , 2005 , 24 , 769 .
18.
Yuan P.
,
Liu S.H.
,
Wang X.
, and
Yin J.
, Organometallics , 2005 , 24 , 1452 .
19.
Bullock R.M.
,
Lemke F.R.
, and
Szalda D.J.
, J. Am. Chem. Soc. , 1990 , 112 , 3244 .
20.
Lemke F.R.
,
Szalda D.J.
, and
Bullock R.M.
, J. Am. Chem. Soc. , 1991 , 113 , 8466 .
21.
Jayaprakash K.N.
,
Paresh C.
, and
Amitabha S.
, Organometallics , 1999 , 18 , 3851 .
22.
Yuan P.
,
Wu X.H.
,
Yu G.A.
, and
Liu S.H.
, J. Organomet. Chem. , 2007 , 692 , 3588 .
23.
Liu F.
,
Wu X.H.
,
Xia J.L.
,
Jin S
,
Yu G.A.
,
Liu S.H.
, J Organomet Chem. , 2010 , 695 , 809 .
24.
Xia J.L.
,
Wu X.H.
,
Yu G.A.
,
Liu S.H.
, Organometallics , 2009 , 28 , 2701 .
25.
Wu X.H.
,
Jin S.
,
Liang J.H.
,
Yu G.A.
,
Liu S.H.
, Organometallics , 2009 , 28 , 2450 .