Nine heterobimetallic homoleptic diethanolaminate complexes of the types: [Nb(Rdea)3{Ta(Rdea)2}] (where Rdea = RN(CH2CH2O-)2 and R = H, 2; Me, 3; Bun, 4; Ph, 5), [Nb(Rdea)3{Al(Rdea)}] (R = H, 6; Me, 7; Bun, 8; Ph, 9), and [Nb(Phdea)3{Sb(Phdea)}] 10 have been prepared for the first time by the equimolar reactions of [Nb(Rdea)2(RdeaH)] with [Ta(Rdea)2(OPri)] or [Al(Rdea)(OPri)] or [Sb(Phdea)(OPri)] in benzene. The structural features of the new complexes have been elucidated by IR and NMR (1H, 27Al) spectroscopies.
MehrotraR.C., and KapoorP.N., J. Indian Chem Soc., 1967, 44, 468.
2.
MehrotraR.C., and KapoorP.N., Indian J. Chem., 1967, 5, 505.
3.
BradleyD.C., MehrotraR.C., RothwellI.P., and SinghA., Alkoxo and Aryloxo Derivatives of Metals, Academic Press, London, 2001.
4.
BabonneauF., LeausticA., and LivageJ., Better Ceramics Through Chemistry III, edited by BrinkerC.J., ClarkD.E., and UlrichD.R., Mater. Res. Soc., Pittsburgh, PA, 1988, 317.
5.
ZhengH., ColbyM.W., and MackenzieJ.D., Better Ceramics Through Chemistry III, edited by BrinkerC.J., ClarkD.E., and UlrichD.R., Mater. Res. Soc., Pittsburgh, PA, 1988, 537.
6.
SanchezC., LivageJ., HenryM., and BabonneauF., J. Non-Cryst. Solids, 1988, 100, 65.
7.
TakahashiY., NiwaK., KobayashiK., and MatsukiM., Yogyo Kyokaishi, 1987, 95, 942; Chem. Abstr., 1987, 107, 203776 h.
KleinL.C., Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics and Speciality Shapes, Noyes, Park Ridge, N.J., 1988.
10.
BrinkerC.J., and SchererG.W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, Academic Press, New York, 1990.
11.
SinghA., and MehrotraR.C., Coord. Chem. Rev., 2004, 248, 101.
12.
GhadwalR.S., SinghA., and MehrotraR.C., Transition Met. Chem., 2005, 30, 836.
13.
SharmaM.K., SinghA., and MehrotraR.C., Transition Met. Chem., 2002, 27, 115.
14.
SharmaN.B., SinghA., and MehrotraR.C., Main Group Met. Chem., 2004, 27, 211.
15.
SharmaN.B., SinghA., and MehrotraR.C., J. Chem. Res., 2004, 450.
16.
SharmaM., SinghA., and MehrotraR.C., Indian J. Chem.1999, 38A, 1209.
17.
SharmaM., SinghA., and MehrotraR.C., Polyhedron, 2000, 19, 77.
18.
SharmaK., SharmaM., SinghA., and MehrotraR.C., Transition Met. Chem., 2002, 27, 326; Main Group Met Chem., 2003, 26, 131; Indian J. Chem., 2003, 42A, 493.
19.
GhadwalR.S., SinghA., and MehrotraR.C., J. Chem. Res., 2005, 352.
20.
SharmaN.B., SinghA., and MehrotraR.C., Transition Met. Chem., 2005, 30, 103.
21.
SharmaM.K., SinghA., and MehrotraR.C., Indian J. Chem.2000, 39A, 410.
(a) GhadwalR.S., and SinghA., Indian J. Chem.2005, 44A, 2439; (b) M.K. Sharma, PhD Thesis, University of Rajasthan, Jaipur, India (2000).
24.
GhadwalR.S., SinghA., and MehrotraR.C., Main Group Met. Chem., 2004, 27, 199.
25.
StewartJ.E., J. Chem. Phys., 1959, 30, 1259.
26.
KatritzkyA.R., and JonesR.A., J. Chem. Soc., 1959, 3674.
27.
(a) GurianP.L., CheathamL.K., ZillerJ.W., and BarronA.R., J. Chem. Soc., Dalton Trans., 1991, 1449; (b) N.B. Sharma, A. Singh and R.C. Mehrotra, Main Group Met. Chem., 2004, 27, 191.
28.
PerrinD.D., ArmargoW.L.F., and PerrinD.R., Purification of Laboratory Chemicals, 2nd edn, Pergmon Press, New York, 1980.
29.
BradleyD.C., ChakravartiB.N., and WardlawW.J. Chem. Soc., 1956, 4439.
30.
BradleyD.C., Nature, 1954, 174, 323.
31.
BrownL.M., and MazdiyasniK.S., Inorg. Chem., 1970, 9, 2783.
32.
BrillT.B., and CampbellN.C., Inorg. Chem., 1973, 12, 1884.
33.
VogelA.I., A. Textbook of Quantitative Inorganic Analysis, 5th edn. Longmann, London, 1978.
34.
(a) AdamsC.A., and NichollasJ.R., Analyst, 1929, 54(634), 2; (b) D.C. Bradley, F.M.A. Halim and W. Wardlaw, J. Chem. Soc., 1950, 340; (c) R.C. Mehrotra, J. Indian Chem. Soc., 1953, 30, 585.
