Abstract
A series of transition metal-n cyanopyridines (i.e. pyridine-n-carbonitrile; n = 2, 3, 4) complexes with one-dimensional (1-D) structures, [CuCl2(pyridine-3-carbonitrile)2] n , [CuCl2(pyridine-4-carbonitrile)2] n and [CoCl2(pyridine-4-carbonitrile)2] n , have been synthesised via hydrothermal reactions and structurally characterised by single-crystal X-ray diffraction. All these complexes feature infinite 1-D chain-like structures. Photoluminescent investigation reveals that the title complexes display strong emissions which may originate from π→π* charge-transfer interaction of the ligands.
References
1.
Wang Z.
,
Chen G.
, and
Ding K.
, Chem. Rev. , 2009 , 109 , 322 .
2.
Clavier G.
, and
Audebert P.
, Chem. Rev. , 2010 , 110 , 3299 .
3.
Chen E.Y.-X.
, Chem. Rev. , 2009 , 109 , 5157 .
4.
Morsali A.
, and
Masoomi M.Y.
, Coord. Chem. Rev. , 2009 , 253 , 1882 .
5.
Yan Y.
, and
Huang J.
, Coord. Chem. Rev. , 2010 , 254 , 1072 .
6.
Lin P.
,
Henderson R.A.
,
Harrington R.W.
,
Clegg W.
,
Wu C.-D.
, and
Wu X.-T.
, Inorg. Chem. , 2004 , 43 , 181 .
7.
Goher M.A.S.
,
Mautner F.A.
,
Abu-Youssef M.A.M.
,
Hafez A.K.
,
Badr A.M.-A.
, and
Gspan C.
, Polyhedron , 2003 , 22 , 3137 .
8.
Zhang W.
,
Jeitler J.R.
,
Turnbull M.M.
,
Landee C.P.
,
Wei M.
, and
Willett R.D.
, Inorg. Chim. Acta , 1997 , 256 , 183 .
9.
Hanika-Heidl H.
,
Etaiw S.E.H.
,
Ibrahim M. Sh.
,
El-din A.S.B.
, and
Fischer R.D.
, J. Organomet. Chem. , 2003 , 684 , 329 .
10.
Cotton F.A.
, and
Wang W.
, Inorg. Chem. , 1982 , 21 , 2675 .
11.
Follett A.D.
,
McNabb K.A.
,
Peterson A.A.
,
Scanlon J.D.
,
Cramer C.J.
, and
McNeill K.
, Inorg. Chem. , 2007 , 46 , 1645 .
12.
Du M.
,
Wang Q.
,
Wang Y.
,
Zhao X.J.
, and
Ribas J.
, J. Solid State Chem. , 2006 , 179 , 3926 .
13.
Galet A.
,
Munoz M.C.
, and
Real J.A.
, Inorg. Chem. , 2006 , 45 , 4583 .
14.
Vamvounis G.
,
Caplan J.F.
,
Cameron T.S.
,
Robertson K.N.
, and
Aquino M.A.S.
, Inorg. Chem. Acta , 2000 , 304 , 87 .
15.
Daran J.
,
Jeannin Y.
, and
Martin L.M.
, Inorg. Chem. , 1980 , 19 , 2935 .
16.
Rigaku
(2002 ), CrystalClear Version 1.35 , Rigaku Corporation .
17.
Siemens
(1994 ), SHELXTL™ Ver. 5 Reference Manual, Siemens Energy & Automation Inc. , Madison, Wisconsin, USA.
18.
Zhang W.
,
Leng X.
, and
Sun W.-H.
, J. Chem. Res. , 2003 , 808 .
19.
Vedernikov A.N.
,
Wu P.
,
Huffman J.C.
, and
Caulton K.G.
, Inorg. Chim. Acta , 2002 , 330 , 103 .
20.
Han L.
,
Cui Y.
,
Li Y.
,
Sun W.-H.
,
Du J.
, and
Li J.
, J. Chem. Res. , 2003 , 157 .
21.
Ketcham K.A.
,
Garcia I.
,
Bermejo E.
,
Swearingen J.K.
,
Castineiras A.
, and
West D.X.
, Z. Anorg. Allg. Chem. , 2002 , 628 , 409 .
22.
Begley M.J.
,
Hubberstey P.
, and
Moore C.H.M.
, J. Chem. Res. , 1986 , 172 , 1501 .
23.
Li S.-A.
,
Xia J.
,
Yang D.-X.
,
Xu Y.
,
Li D.-F.
,
Wu M.-F.
, and
Tang W.-X.
, Inorg. Chem. , 2002 , 41 , 1807 .
24.
Bigoli F.
,
Lanfranchi M.
, and
Pellinghelli M.A.
, J. Chem. Res. , 1990 , 214 , 1712 .
25.
Zhao Q.-H.
,
Liao D.-Z.
,
Jiang Z.-H.
,
Yan S.-P.
,
Gao S.
, and
Sun B.-W.
, J. Coord. Chem. , 2002 , 55 , 293 .
26.
Dong Y.-B.
,
Smith M.D.
,
Layland C.
, and
Loye H.-C.zur
, Inorg. Chem. , 1999 , 38 , 5027 .
27.
Du M.
,
Zhao X.-J.
,
Batten S.R.
, and
Ribas J.
, Cryst. Growth & Des. , 2005 , 5 , 901 .
28.
Galet A.
,
Munoz M.C.
, and
Real J.A.
, Inorg. Chem. , 2006 , 45 , 4583 .
29.
Liu C.W.
,
Hung C.-M.
,
Santra B.K.
,
Chu Y.-H.
, and
Wang J.-C.
,
Lin Z.
, Inorg. Chem. , 2004 , 43 , 4306 .
30.
Su B.-Q.
,
Xian L.
,
Zhang B.
, and
Song H.-B.
, J. Chem. Res. 2005 , 101 .
31.
O'Keeffe M.
, and
Brese N.E.
, J. Am. Chem. Soc. , 1991 , 113 , 3226 .
32.
Champouret Y.D.M.
,
Fawcett J.
,
Nodes W.J.
,
Singh K.
, and
Solan G.A.
, Inorg. Chem. , 2006 , 45 , 9890 .
33.
Telfer S.G.
,
Sato T.
,
Kuroda R.
,
Lefebvre J.
, and
Leznoff D.B.
, Inorg. Chem. , 2004 , 43 , 421 .
34.
Veith M.
,
Muller A.
,
Stahl L.
,
Notzel M.
,
Jarczyk M.
, and
Huch V.
, Inorg. Chem. , 1996 , 35 , 3848 .
35.
Wang H.
,
Zhang S.
,
Yang J.
,
Deng Y.
, and
Lu X.
, J. Chem. Res. , 2006 , 384 .
36.
Jain S.L.
,
Bhattacharyya P.
, and
Pritchard R.G.
, J. Chem. Res. , 2006 , 376 .
37.
Funck K.E.
,
Hilfiger M.G.
,
Berlinguette C.P.
,
Shatruk M.
,
Wernsdorfer W.
, and
Dunbar K.R.
, Inorg. Chem. , 2009 , 48 , 3438 .
38.
Chakrabarty R.
,
Sarmah P.
,
Saha B.
,
Chakravorty S.
, and
Das B.K.
, Inorg. Chem. , 2009 , 48 , 6371 .
39.
Dawe L.N.
,
Shuvaev K.V.
, and
Thompson L.K.
, Inorg. Chem. , 2009 , 48 , 3323 .
40.
Akine S.
,
Dong W.
, and
Nabeshima T.
, Inorg. Chem. , 2006 , 45 , 4677 .