Deuterium kinetic isotope effects support a mechanism for the Boyland–Sims oxidation involving a nucleophilic displacement by the amine on the peroxide oxygen.
BehrmanE.J. (2006) Beilstein J. Org. Chem., 2, 22.
2.
MarjanovićB., JuranićI., and Ćirić-MarjanovićG. (2011) J. Phys. Chem. A, 115, 3536.
3.
BehrmanE.J. (2011) J. Phys. Chem. A, 115, 7863.
4.
MarjanovićB., JuranićI., and Ćirić-MarjanovićG. (2011) J. Phys. Chem. A, 115, 7865.
5.
SabesanA., and VenkatasubramanianN. (1971) Aust. J. Chem., 24, 1633.
6.
BasoloF., and PearsonR.D. (1967) Mechanisms of inorganic reactions, 2nd edn, p. 387. Wiley, New York.
7.
BehrmanE.J. (1967) J. Am. Chem. Soc., 89, 2424.
8.
LaughtonP.M., and RobertsonR.E. (1969) Solvent isotope effects for equilibria and reactions. In: CoetzeeJ.F., and RitchieC.D. (eds), Solute-solvent interactions, pp. 424–432. Marcel Dekker, New York.
9.
ReichardtC. (2003) Solvents and solvent effects in organic chemistry, 3rd edn, pp. 315–317. Wiley-VCH, Weinheim.
10.
HuangH., SommerfeldD., DunnB.C., LloydC.R., and EyringE.M. (2001) J. Chem. Soc., Dalton Trans., 1301.
11.
HuangH., SommerfeldD., DunnB.C., EyringE.M., and LloydC.R. (2001) J. Phys. Chem. A, 105, 3536.
12.
BehrmanE.J., and WalkerP.P. (1962) J. Am. Chem. Soc., 84, 3454.