Abstract
A variety of terminal arylacetylenes have been conveniently synthesised in good to high yields by Stille coupling of aryl halides with ethynyltributylstannane catalysed by a MCM-41-supported bidentate phosphine palladium(O) complex in an aqueous medium and under air. Our system not only avoids the requirement for water-free and oxygen-free conditions, but also solves the basic problem of palladium catalyst reuse.
Keywords
References
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