Abstract
1,3-bis(2-pyridylimino)isoindolines (BPI) with N-donor groups and long alkyl chains were synthesised by DCC-activated esterification of mercaptoethanol-substituted bis(pyridylimino)isoindole with carboxylic acid derivatives (pyridine-4-carboxylic acid, nonanoic acid). Homoleptic iron(II) complex was synthesised by reaction of BPI with Fe(ClO4)2 in acetone: chloroform. The new compounds were characterised by elemental analyses, FT-IR, 1H NMR, 13C NMR and UV-Vis spectral data.
References
1.
Parshall G.W.
, and
Ittel S.D.
, Homogeneous catalysis, the applications and chemistry of catalysis by soluble transition metal complexes. Wiley-Interscience , New York , 1992 .
2.
Meder M.B.
,
Siggelkow B.A.
, and
Gade L.H.
, Z. Anorg. Allg. Chem. , 2004 , 630 , 1962 .
3.
Balogh-Hergovich E.
,
Kaizer J.
,
Speier G.
,
Huttner G.
, and
Jacobi A.
, Inorg. Chem. , 2000 , 39 , 4224 .
4.
Balogh-Hergovich E.
, and
Speier G.
, J. Mol. Catal. A: Chem. , 2005 , 230 , 79 .
5.
Meder M.B.
, and
Gade L.H.
, Eur. J. Inorg. Chem. , 2004 , 2716 .
6.
Kaizer J.
,
Pap J.
,
Speier G.
,
Reglier M.
, and
Giorgi M.
, Transition Met. Chem. , 2004 , 29 , 630 .
7.
Siggelkow B.
,
Meder M.B.
,
Galka C.H.
, and
Gade L.H.
, Eur. J. Inorg. Chem. , 2004 , 3424 .
8.
Siggelkow B.A.
, and
Gade L.H.
, Z. Anorg. Allg. Chem. , 2005 , 631 , 2575 .
9.
Meder M.B.
,
Haller I.
, and
Gade L.H.
, Dalton Trans. , 2005 , 1403 .
10.
Meder M.
,
Galka C.H.
,
Gade L.H.
, Monatsh. Chem. , 2005 , 136 , 1693 .
11.
Siegl W.O.
, J. Heterocyclic Chem. , 1981 , 18 , 1613 .
12.
Balogh-Hergovich E.
,
Speier G.
,
Reglier M.
,
Giorgi M.
,
Kuzmann E.
, and
Vertes A.
, Eur. J. Inorg. Chem. , 2003 , 1735 .
13.
Selvi P.T.
,
Stoeckli-Evans H.
, and
Palaniandavar M.
, J. Inorg. Biochem. , 2005 , 99 , 2110 .
14.
Anderson O.P.
,
La Cour A.
,
Dodd A.
,
Garrett A.D.
, and
Wicholas M.
, Inorg. Chem. , 2003 , 42 , 122 .
15.
Dietrich B.L.
,
Egbert J.
,
Morris A.M.
,
Wicholas M.
,
Anderson O.P.
, and
Miller S.M.
, Inorg. Chem. , 2005 , 44 , 6476 .
16.
Marks D.N.
,
Siegl W.O.
, and
Gagne R.R.
, Inorg. Chem. , 1982 , 21 , 3140 .
17.
Gagne R.R.
,
Marritt W.A.
,
Marks D.N.
, and
Siegl W.O.
, Inorg. Chem. , 1981 , 20 , 3260 .
18.
Gagne R.R.
,
Gall R.S.
,
Lisensky G.C.
,
Marsh R.E.
, and
Speltz L.M.
, Inorg. Chem. , 1979 , 18 , 771 .
19.
Şener M.K.
, Asian J. Chem. , 2007 , 19 , 1870 .
20.
Balogh-Hergovich E.
,
Speier G.
,
Reglier M.
,
Giorgi M.
,
Kuzmann E.
, and
Vertes A.
, Inorg. Chem. Commun. , 2005 , 8 , 457 .
21.
Gagne R.R.
, and
Marks D.N.
, Inorg. Chem. , 1984 , 23 , 65 .
22.
Kaizer J.
,
Barath G.
,
Speier G.
,
Reglier M.
, and
Giorgi M.
, Inorg. Chem. Commun. , 2007 , 10 , 292 .
23.
Şener M.K.
,
Gül A.
, and
Koçak M.B.
, J. Porphyrins Phthalocyanines , 2003 , 7 , 617 .
24.
Şener M.K.
,
Koca A.
,
Gül A.
, and
Koçak M.B.
, Polyhedron , 2007 , 26 , 1070 .
