Abstract
Complexes of iron(III), ruthenium(III) and rhodium(III) with three new tetraaza macrocyclic ligands, oxo4bzo3[14]triene-N4 [TBTAC14Tone], oxo4bzo2[14]diene-N4 [DBTAC14Tone] and oxo4bzo2[15]diene-N4 [DBTAC15Tone] have been prepared and characterised. The complexes are found to have the formulae [FeLCl2]Cl. 2H2O, [RuLCl2]Cl. 3H2O and [RhLCl2]Cl. 2H2O. The cations adopt a trans-dichloro configuration with the six-coordinated trivalent metal ions in a pseudo-octahedral geometry.
Keywords
References
1.
Bishop D.G.
, and
Reed M. L.
, in K. C. Smith (Ed.), Photochem. Photobiol. Rev. , 1976 , 1 , 1 .
2.
Foote C.S.
,
Chang Y. C.
, and
Denny R. W.
, J. Am. Chem. Soc. , 1970 , 92 , 5216 , 5218 and refs therein.
3.
(a)
Wallace W.J.
, and
Caughey W. S.
, Biochem. Biophys. Res. Commun. , 1975 , 62 , 561 .
4.
Collman J.P.
,
Gagne R. R.
,
Halbert T. R.
,
Marchon J. C.
, and
Reed C.
, J. Am. Chem. Soc. , 1974 , 95 , 5595 .
5.
Collman J.P.
,
Gagne R. R.
, and
Reed C. A.
, J. Am. Chem. Soc. , 1974 , 96 , 2629 .
6.
Takano T.
,
Trus B. L.
,
Mandel N.
,
Mandel G.
,
Kallai O. B.
,
Swanson R.
, and
Dickerson R. E.
, J. Biol. Chem. , 1977 , 252 , 776 .
7.
(a)
Basolo F.
,
Hoffman B. M.
, and
Ibers J. A.
, Acct. Chem. Res , 1975 , 8 , 384 .
8.
Yatshimirskii K.B.
,
Tikhonova L. P.
,
Zakrevskaja L. N.
, and
Lampella J. D.
, Theor Eksp Khim , 1982 , 18 , 439 .
9.
Owston P.G.
,
Peters R.
,
Ramsammy E.
,
Taskar P. A.
, and
Trotter J.
, J. Chem. Soc., Chem. Commun. , 1980 , 1218 .
10.
Swamy S.J.
,
Veera Paratap B.
,
Nagaraju D.
,
Suresh K.
, and
Someshwar P.
, Tetrahedron , 2003 , 59 , 10093 .
11.
(a)
Curtis N.F.
, Coord Chem Rev , 1983 , 1 , 3 .
12.
Goedken V.L.
,
Merrell P. H.
, and
Busch D. H.
, J. Am. Chem. Soc. , 1972 , 94 , 3397 .
13.
Babrowiak J.C.
,
Merrell P. H.
, and
Busch D. H.
, Inorg. Chem. , 1972 , 11 , 1979 .
14.
(a)
Allan J.R.
, and
Veitahe P. M.
, J. Therm. Anal. , 1971 , 27 , 3 .
15.
Swamy S.J.
, and
Dharma Reddy A.
, J. Ind. Chem. Soc. , 2000 , 77 , 336 and refs therein.
16.
(a)
Ishimare S.
, J. Chem. Soc. Jap. , 1934 , 55 , 201 .
17.
Swamy S.J.
, and
Raveender Reddy S.
, Indian J. Chem. , 2001 , 40A , 1093 .
18.
Swamy S.J.
,
Dharmapuri Y.
, and
Kumar B. K.
, Ind. J. Chem. , 1995 , 34A , 811 .
19.
Ellington H.J. T.
, J. Soc. Chem. Ind. , 1944 , 63 , 125 .
20.
(a)
Ibrahim M.
,
El-Asmy A.
,
Bekheit M.
, and
Motafa M.
, Trans. Met. Chem. , 1984 , 10 , 103 .
21.
Sandhu S.S.
,
Manhas B. S.
,
Mittal M. R.
, and
Parmer S. S.
, Ind. J. Chem. , 1984 , 9 , 103 .
22.
(a)
Swamy S.J.
, and
Bhaskar K.
, Ind. J. Chem. , 1999 , 38A , 961 .
23.
Goeta A.E.
,
Howard J. A. K.
,
Maffeo D.
,
Puschmann H.
, and
Williams J. A. G.
,
Yufit D. S.
, J. Chem. Soc. Dalton Trans. , 2000 , 1873 .
24.
Van der Elsken J.
, and
Robinson D. W.
, Spectrochim. Acta. , 1961 , 17 , 1249 .
25.
(a)
Nakamoto K.
,
Mc Carthy P. J.
, and
Miniatas B.
, Spectrochim. Acta. , 1965 , 21 , 379 .
26.
Ghosh B.
, and
Bandopadhyay T. K.
, Trans. Met. Chem. , 1986 , 11 , 467 .
27.
Chandrasekhar V.
, and
Agarwal R. C.
, J. Inorg. Nucl. Chem. , 1979 , 41 , 1057 .
28.
Lewis J.
,
Nyholm R. J.
, and
Rodley G. A.
, J. Chem. Soc. , 1965 , 1483 .
29.
Mialane P.
,
Girerd J. J.
,
Guilhem J.
, and
Rchertanov L.
, Inorg. Chim. Acta. , 2000 , 298 , 38 .
30.
Greenwood N.N.
, and
Earnshaw A.
, Chemistry of Elements , Pergamon Press , Oxford , 1989 , p, 1263 and p. 1310.
31.
Vogel A.I.
, A Text Book of Quantitative Inorganic Analysis , ELBS and Longman , London , 3rd Edn 1975 , pp. 700 .