The kinetics of oxidation of diethylene glycol (DG) by dihydroxyditelluratoargentate(III) (DDA) is studied spectrophotometrically between 298.2K and 313.2K in alkaline medium. A mechanism involving a one–step two–electron transfer has been proposed The activation parameters and the rate constants of the rate-determining step are calculated.
FeiglF., Spot Tests in Organic Analysis, Elsevier Publishing Co, New York, 1956, 208.
8.
JinJ.J., Kinetics Principle of Chemical Reaction in Liquid Phase, Shanghai: Science and Technology Press, 1984, p. 29.
9.
The Teaching and Research Section of Analytical Chemistry in Zhongnan Mining Institute, Handbook of Analytical Chemistry Science press., Beijing: 1984, p. 567.
