Abstract
The orientation of the products of nitrosation: nitration and bromination of the methanesulfonamides of the six isomeric dimethylanilines have been established by 1H NMR nuclear Overhauser experiments.
References
1.
Shriner R.L.
,
Goebel M. T.
, and
Marvel C. S.
, J. Am. Chem. Soc. , 1932 , 54 , 5470 .
2.
Bell F.
, J. Chem. Soc. , 1928 , 2770 .
3.
Bunton C.A.
,
Hughes E. D.
,
Ingold C. K.
,
Jacobs D. I. H.
,
Jones M. H.
,
Minkoff G. J.
, and
Reed R. I.
, J. Chem. Soc. , 1950 , 2628 .
4.
Wepster B.M.
, Rec. Trav. Chim. , 1954 , 73 , 809 .
5.
Dadswell H.E.
, and
Kenner J.
, J. Chem. Soc. , 1927 , 1102 .
6.
Ridd J.H.
, Chem. Soc. Rev. , 1991 , 20 , 149 .