Benzyldibutyltelluronium bromide can react with LDA to form benzyldibutyltelluronium ylide in situ, followed by the reaction with aromatic aldehydes, developed a novel method for the stereoselective synthesis of trans-diaryl epoxides.
(a) PetragnaniN., and ComassetoJ. V., Synthesis, 1986, 1; (b) N. Petragnani and J. V. Comasseto, Synthesis, 1991, 815; (c) Y. Tang, Z. F. Chi, Y. Z. Huang, L. X. Dai and Y. H. Yu, Tetrahedron, 1996, 52, 8747; (d) S. Ye, L. Yuan, Z. Z. Huang, Y. Tang and L. X. Dai, J. Org. Chem., 2000, 65, 6257.
2.
(a) HuangX., XieL. H., and WuH., J. Org. Chem., 1988, 53, 4682; (b) Z. Z. Huang, L. W. Wen and X. Huang, Synth. Commun., 1990, 20, 2579.
(a) ReizA.B., NorteyS. O., JordanA. D., MutterM. S.Jr., and MarryanoffB. E., J. Org. Chem., 1986, 51, 3302; (b) D. R. Arnstrong, M. G. Dauidson and D. Meencrieff, Angew. Chem., Int. Ed. Engl., 1995, 34, 478; (c) Y. G. Zhou, A. H. Li, X. L. Hou and L. X. Dai, J. Chem. Soc. Chem. Commun., 1996, 1353.
5.
CampbellS., JohnD., and DarwishD., Can. J. Chem., 1976, 54(2), 193.
6.
FetizonM., HenryY., and ArandaG., Org. Mass. Spectro., 1974, 8, 201.
7.
ReulosD., and TellierS. L., Compt. Rend., 1943, 217, 698.
8.
ShonoT., AkazawaT., and MitaniM., Tetrahedron, 1973, 29(6), 817.
