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Abstract

Arylalkenes undergo photochemical cycloaddition reactions with cyclic enones to give products with specific regio-chemistry and controlled stereochemistry. The regio- and stereo-chemistries can be rationalised in terms of the stability of intermediate radicals.

Keywords

photochemistry cyclic enones regioselection stereoselection cycloaddition bicycloalkanones

References

Part 12: Kelly

J.F.D.J.

, Kelly

J.M.

, and McMurry

T.B.H.

, J. Chem. Soc., Perkin Trans. 2, 1999, 1933.

Kelly

J.M.

, McMurry

T.B.H.

, and Work

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, J. Chem. Soc., Chem. Comm., 1987, 280; J. Chem. Soc., Perkin Trans. 2, 1990, 981.

Photochemistry of Cyclic Enones. Part 13 1 . Intermolecular Addition of Styrene and 1-Phenylprop-1-Enes with 3-Phenylcyclopentenone and 3-Phenylcyclohexenone

Abstract

Keywords

References