AbstractThe effect of solvent on the outer-sphere redox reactions between cobalt(III)-amine complexes and hexacyanoferrate(II) studied in aqueous methanol/1,4-dioxane is discussed quantitatively in terms of various solvent–solvent–solute interactions.Keywordscobalt(III)-amine complexeskinetics of electron transferReferences1. Reichardt C. , Solvents and Solvent Effects in Organic Chemistry, VCH, Weinheim, 1988.2. Swain C.G. , Swain M. S. , Powell A. L. , and Alunni S. , J. Am. Chem. Soc., 1983, 105, 502.3. Kamlet M.J. , Abboud J. M. , Abraham M. H. , and Taft R. W. , J. Org. Chem., 1983, 48, 2877.
