Abstract
A combination of inorganic acidic salts or oxalic acid dihydrate and sodium nitrate in the presence of wet SiO2 was used as an effective oxidising agent for the oxidation of dihydropyridines to their corresponding pyridine derivatives at 40–50 oC with excellent yields.
References
1.
Chavan S.P.
,
Dantale S. W.
,
Kalkote U. R.
,
Jyothirmai V. S.
, and
Kharul R. K.
, Synth. Commun. , 1998 , 28 , 2789 .
2.
Itoh T.
,
Nagata K.
,
Matsuya Y.
,
Miyazaki M.
, and
Ohsawa A.
J. Org. Chem. , 1997 , 62 , 3582 .
3.
(a)
Balogh M.
,
Hermecz I.
,
Meszaros Z.
, and
Laszlo P.
Helv. Chem. Acta , 1984 , 67 , 2270 .
4.
Khadikar B.
, and
Borkat S.
Synth. Commun. , 1998 , 28 , 207 .
5.
Pfister J.R.
Synthesis , 1990 , 689 .
6.
Maquestiau A.
,
Mayence A.
, and
Eynde J. J. V.
Tetrahedron Lett. , 1991 , 32 , 3839 .
7.
Eynde J.J. V.
,
Mayence A.
, and
Maquestiau A.
Tetrahedron , 1992 , 48 , 463 .
8.
Memarian H.R.
,
Sadeghi M. M.
, and
Aliyan H.
Indian J. Chem. , 1998 , 37B , 219 .
9.
(a)
Zolfigol M.A.
Synth. Commun. , 1999 , 29 , 905 .
10.
Zolfigol M.A.
,
Nematollahi D.
, and
Mallackpour S. E.
Synth. Commun. , 1999 , 29 , 2277 .
11.
Zolfigol M.A
, and
Mallackpour S. E.
Synth. Commun. , 1999 , 29 , 4061 .
12.
Mallakpour S.E.
, and
Zolfigol M. A.
Ind. J. Chem. , 1995 , 34B , 183 .
13.
Zolfigol M.A.
,
Iranpoor N.
, and
Firouzabadi H.
Orient. J. Chem. , 1998 , 14 , 369 .
14.
Zolfigol M.A.
,
Ghaemi E.
, and
Madrakian E.
Synth. Commun. , 2000 , 30 (10 ), in press.
15.
Dorfman Y.A.
, and
Aleshkova M. M.
Russ. Org. Chem. , 1998 , 34 , 217 .
16.
Loev B.
, and
Snader K. M.
J. Org. Chem. , 1965 , 30 , 1914 .
