The study of inorganic solid-state electronic and vibronic transitions at low temperatures, by a wide-range Fourier transform spectrometer, covering the range 150 to 47,500 cm−1, with a resolution between 0.5 and 2.0 cm−1, is described. The types of electronic transitions of molecular ions are given, and the link between calculation and experimental measurement is highlighted. Factors contributing to the linewidths in solid-state electronic absorption spectrometry are identified. The instrumental techniques for sample preparation and the recording of spectra at low temperature are described, together with parameters affecting the resolution, precision, and calibration of a Fourier transform instrument. Problems which may arise from sample heating, spectrum fringing, aliasing, and the operation of spectrum subtraction are discussed. Some applications of the Fourier transform spectrometer are presented.
FlintC. D., in Advances in Infrared and Raman Spectroscopy, ClarkR. J. H.HesterR. E., Eds. (Elsevier, New York, 1976), Vol. 4 p. 53.
8.
EdelsteinN., in Fundamental and Technological Aspects of Organo-f-Element Chemistry, MarksT. J.FragalaI. L., Eds. (D. Reidel, Dordrecht, 1985), pp. 229–276.
9.
DenningR. G., in Vibronic Processes in Inorganic Chemistry, FlintC. D. Ed. (Kluwer Academic Publishers, Dordrecht, 1989), p. 111.
10.
PiephoS.SchatzP., Group Theory in Spectroscopy with Applications to Magnetic Circular Dichroism (Wiley, New York, 1983).
11.
Fourier Transform Infrared Spectroscopy, FerraroJ. R.BasileL. J., Eds. (Academic Press, New York, 1985), Vols. 1–4.
12.
GriffithsP. R.De HasethJ. A., Fourier Transform Infrared Spectroscopy (Wiley, New York, 1986).
13.
GriffithsP. R., Chemical Infrared Fourier Transform Spectroscopy (Wiley, New York, 1975).
14.
Advances in Applied Fourier Transform Infrared Spectroscopy, MackenzieM. W. Ed. (Wiley, New York, 1988).
15.
DenningR. G.SnellgroveT. R.WoodwarkD. R., Molec. Phys.30, 1819 (1975).
16.
IngleJ. D.CrouchS. R., Spectrochemical Analysis (Prentice-Hall, Englewood Cliffs, New Jersey, 1988).
17.
HinchliffeA.MunnR. W., Molecular Electromagnetism (Wiley, New York, 1985).
18.
PottsW. J.SmithA. L., Appl. Opt.6, 257 (1967).
19.
PeacockR. D., “The Intensities of Lanthanide f-f Transitions,” in Structure and Bonding (Springer-Verlag, New York, 1975), Vol. 22.
20.
SztuckiJ., Chem. Phys. Lett.203, 383 (1993).
21.
AcevedoR.VasquezS. O.FlintC. D., Molec. Phys.74, 853 (1991).
