A method for examining the photo-induced polymerization of photoresists and solder masks, at the substrate/photopolymer interface, using attenuated total reflectance (ATR) and infrared spectroscopy is discussed. The method is especially useful for dry film photoresists and gives information concerning cure levels affected by exposure dose and photoresist thickness. The photoprocessing of Vacrel® 8100 series solder mask and Riston® 3100 series photoresists from Dupont are used as examples.
DeForestW. S., Photoresist (McGraw-Hill, New York, 1975).
2.
SteppanH.BuhrG. and VollmannH, Angew. Chem., I.E.21, 455 (1982).
3.
ReiserA., Photoreactive Polymers: The Science and Technology of Resists (John Wiley & Sons, New York, 1989).
4.
GervayJ. E., US 4621043 (1986).
5.
FuernissS. J., US 4497889 (1985).
6.
FinterJ.HanioticZ.MeierK. and ZweifelH, J. Imaging Sci.30, 259 (1986).
7.
GoldrickM. R. and PlaugerL. R, Photo. Sci. Eng.17, 386 (1973).
8.
LiebermanR. A., J. Radiat. Cur.13 (1981).
9.
McGinnisV. D., J. Radiat. Cur.3 (1975).
10.
McGinnisV. D. and TingV. W, J. Radiat. Cur.14 (1975).
11.
AppeltB. K., Poly. Eng. Sci.23, 125 (1983).
12.
Zeim LeD. D., J. Radiat Cur.2 (1985).
13.
CollinsG. L.YoungD. A. and CostanzaJ. R, J. Coating Technol.48, 48 (1976).
14.
PlewsG. and PhillipsR, J. Coating Technol.51, 69 (1979).
15.
Unpublished data, R. W. Snyder.
16.
AllenG. M. and DrainK. F, in Radiation Curing of Polymeric Materials, ACS Symposium Series 417, HoyleC. E. and KinstleJ. F, Eds. (American Chemical Society, Washington, D.C., 1990), pp. 242–257.
17.
ThomasG. A. and WebersV. J, J. Imaging Sci.29, 112 (1985).
18.
GutierrezA. R. and CoxR. J, Poly. Photochem.7, 517 (1986).
19.
GatechairL. R. and TiefenthalerA. M, in Radiation Curing of Polymeric Materials, ACS Symposium Series 417, HoyleC. E. and KinstleJ. F, Eds. (American Chemical Society, Washington, D.C., 1990), pp. 27–42.
20.
NobbsJ. H. and OldringP. K. T, in Radiation Curing of Polymeric Materials, ACS Symposium Series 417, HoyleC. E. and KinstleJ. F, Eds. (American Chemical Society, Washington, D.C., 1990), pp. 43–58.
21.
“Vacrel 8100 Photopolymer Film Solder Mask: End Use Properties and Test Data,”Dupont Product Literature (E. I. Dupont de Nemours & Co. Inc., Wilmington, Delaware).
22.
“Riston 3100 Photopolymer Film Resist,”Dupont Product Literature (E.I. Dupont de Nemours & Co. Inc., Wilmington, Delaware).
23.
HarrickN. J., Internal Reflection Spectroscopy (Harrick Scientific Corp., Ossining, New York, 1979), p. 30.