Relative populations of excited states of He(I) in reduced-pressure ICPs have been shown to obey Fermi-Dirac statistical counting. A single thermodynamic temperature—2000 K—defines the distribution. The experimental relative populations and the Fermi-Dirac distributions agree within fractions of one percent.
RiceO. K., Statistical Mechanics, Thermodynamics and Kinetics (Freeman and Co., New York, 1967), Chap. 14.
3.
FermiE., Z. Physik36, 902 (1926).
4.
PaulingL. and WilsonE. B., Introduction to Quantum Mechanics (McGraw-Hill, New York, 1935), pp. 219–221.
5.
LeightonR. B., Principles of Modern Physics (McGraw-Hill, New York, 1959), p. 350.
6.
HillT. L., An Introduction to Statistical Thermodynamics (Addison-Wesley Publishing Co., Reading, Massachusetts, 1960), Chaps. 7 and 22.
7.
GreenbergO. W. and MessiahA. M. L., Phys. Rev.138, B1155 (1965), and references therein.
8.
BandW., An Introduction to Quantum Statistics (D. van Nostrand Co., New York, 1955), p. 156.
9.
MillerD. C.FanninH. B.FleitzP. A., and SeliskarC. J., Appl. Spectrosc.40, 611 (1986).
10.
FanninH. B.MillerD. C., and SeliskarC. J., Appl. Spectrosc.41, 173 (1987).
11.
FanninH. B.SeliskarC. J., and MillerD. C., Appl. Spectrosc.41, 621 (1987).
12.
FanninH. B., Doctoral Dissertation, University of Cincinnati (1988). To be available on microfilm. Extensive details of the fit are given.
13.
Inductively Coupled Plasma Emission Spectroscopy—Part 2, BoumansP. W. J. M., Ed. (John Wiley and Sons, New York, 1987), Chaps. 9 and 10, but especially Sec. 10.5.