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Abstract

The synthesis of the electronic and infrared spectra of di-2-pyridyl ketone salicyloylhydrazone (DPKSH) and di-2-pyridyl ketone benzoylhy-drazone (DPKBH) is reported. Ultraviolet absorption spectra have been applied for determining the dissociation constants: DPKSH, pK₁ = 3.5 and pK₂ = 6.85; DPKBH, pK₁ = 2.75 and pK₂ = 10.6. These pK_a values are interpreted as a function of the ortho-position of the OH group. Chelating properties of both tridentate ligands have been investigated. DPKSH forms a larger number of metal chelates in acidic media than does DPKBH. Also, it is concluded that DPKSH is a more suitable compound than DPKBH to preconcentrate and to determine heavy metal ion traces as it is inferred from the data obtained by flame AAS.

Keywords

Aroylhydrazones Tridentate ligands Dissociation constants Metal chelates Spectrophotometry Atomic absorption spectroscopy Liquid-liquid extraction Metal preconcentration

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Ligands with the “ONNN” Group as Chelating and Preconcentrating Substances of Heavy Metal Ions: Aroylhydrazone Derivatives from Di-2-Pyridyl Ketone

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