Abstract
Inelastic electron tunneling spectroscopy (IETS) was utilized to study hydridotriosmium decacarbonyl supported on an activated alumina surface. Triosmium dodecacarbonyl was adsorbed under a variety of conditions to give a surface-linked species. The bridging hydrogen observed at 1509 cm is in accord with previous observations. Use of IETS to study supported metal cluster catalysts is critical to the rational design of novel catalysts.
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References
1.
DeCanio
S. J.
Foley
H. C.
Dybowski
C.
, and
Gates
B. C.
, J. Chem. Soc., Chem. Commun. 1372 (1982 ).
2.
Via
G. H.
Sinfelt
J. H.
, and
Lytle
F. W.
, J. Chem. Phys. 71 , 690 (1979 ).
3.
Psaro
R.
Ugo
R.
Zanderighi
G. M.
Besson
B.
Smith
A. K.
, and
Basset
J. M.
, J. Organometal. Chem. 213 , 215 (1981 ).
4.
Hansma
P. K.
, Phys. Rep. 30 , 145 (1977 ).
5.Tunneling Spectroscopy ,
Hansma
P. K.
, Ed. (Plenum , New York , 1982 ).
6.Inelastic Electron Tunneling Spectroscopy ,
Wolfram
T.
, Ed. (Springer-Verlag , New York , 1978 ).
7.
Weinberg
W. H.
, Annu. Rev. Phys. Chem. 29 , 115 (1978 ).
8.
Lewis
B.
and
Weinberg
W. H.
, Surf. Sci. 41 , 142 (1974 ).
9.
Hansma
P. K.
, in Tunneling Spectroscopy ,
Hansma
P. K.
, Ed. (Plenum , New York , 1982 ), p. 14 .
10.
Satterfield
C. H.
, Heterogeneous Catalysis (McGraw-Hill , New York , 1980 ).
11.
Evans
H. E.
Bowser
W. M.
, and
Weinberg
W. H.
, Surf. Sci. 85 , L497 (1979 ).
12.
Kroeker
R. M.
Kaska
W. C.
, and
Hansma
P. K.
, J. Catal. 57 , 72 (1979 ).
13.
Bayman
A.
Hansma
P. K.
Kaska
W. C.
, and
Dubois
L. H.
, Appl. Surf. Sci. 14 , 194 (1982–1983 ).
14.
Kroeker
R. M.
and
Hansma
P. K.
, Catal. Rev.-Sci. Eng. 23 , 553 (1981 ).
15.
Gates
B. C.
and
Lieto
J.
, Chemtech 10 , 195 , 248 (1980 ).
16.
Smith
A. K.
Besson
B.
Basset
J. M.
Psaro
R.
Fusi
A.
, and
Ugo
R.
, J. Organometal. Chem. 192 , C31 (1980 ).
17.
Deeba
M.
and
Gates
B. C.
, J. Catal. , 67 , 303 (1981 ).
18.
Zakharov
V. A.
and
Yermakov
Yu. I.
, Catal. Rev.-Sci. Eng. 19 , 67 (1979 ).
19.
Brenner
A.
, J. Chem. Soc., Chem. Commun. 251 (1979 ).
20.
Anderson
J. R.
Elmes
P. S.
Howe
R. F.
, and
Wainwaring
D. E.
, J. Catal. 50 , 508 (1977 ).
21.
Robertson
J.
and
Webb
G.
, Proc. R. Soc. London, Ser. A 341 , 383 (1974 ).
22.
Knözinger
J. K.
Thornton
E. W.
, and
Wolf
M.
, J. Chem. Soc., Faraday Trans. 1 75 , 1888 (1979 ).
23.
Carturan
G.
and
Strukal
G.
, J. Catal. 57 , 516 (1979 ).
24.
Smith
A. K.
Theolier
A.
Basset
J. M.
Ugo
R.
Commereuc
D.
, and
Chauvin
Y.
, J. Amer. Chem. Soc. 100 , 2590 (1978 ).
25.
Evans
H. E.
and
Weinberg
W. H.
, J. Amer. Chem. Soc. 102 , 872 (1980 ); J. Vac. Sci. Technol. 17 , 47 (1980 ).
26.
Bowser
W. M.
and
Weinberg
W. H.
, J. Amer. Chem. Soc. 103 , 1453 (1981 ).
27.
Bowser
W. M.
and
Weinberg
W. H.
, J. Amer. Chem. Soc. 102 , 4720 (1980 ).
28.
Deeba
M.
and
Gates
B. C.
, J. Catal. 67 , 303 (1981 ).
29.
Gold
H. S.
and
Hilliard
L. J.
, Chem. Biomed. Environ. Instrum. 12 , 1 (1982 ).
30.
Eady
C. R.
Johnson
B. F.
, and
Lewis
J.
, J. Chem. Soc., Dalton Trans. 1706 (1976 ).
31.
Gochin
M.
and
Moss
J. R.
, J. Organometal. Chem. 192 , 409 (1980 ).
32.
Price
W. C.
, J. Chem. Phys. 16 , 894 (1948 ).
33.
Lehmann
W. J.
Wilson
C. O.
Jr.
, and
Shapiro
I.
, J. Chem. Phys. 33 , 590 (1960 ).
34.
Lehmann
W. J.
Wilson
C. O.
Jr.
, and
Shapiro
I.
, J. Chem. Phys. 33 , 1088 (1960 ).
35.
Bradley
G. P.
and
Stobart
S. R.
, J. Chem. Soc., Chem. Commun. 325 (1975 ).
36.
L'Eplattenier
F.
and
Calerazzo
F.
, Inorg. Chem. 7 , 1291 (1968 ).
37.
Peri
J. B.
and
Hannan
R. B.
, J. Phys. Chem. 64 , 1526 (1960 ).
38.
Santacesaria
E.
Gelosa
D.
, and
Carra
S.
, Ind. Eng. Chem., Prod. Res. Dev. 16 , 45 (1977 ).
39.
Kirtley
J. R.
Scalopino
D. J.
, and
Hansma
P. K.
, Phys. Rev. B 14 , 3177 (1976 ).
40.
Adams
R. D.
and
Dawoodi
Z.
, J. Amer. Chem. Soc. 103 , 6510 (1981 ).
41.
Broach
R. W.
and
Williams
J. M.
, Inorg. Chem. 18 , 314 (1979 ).
42.
Adams
R. D.
, Acc. Chem. Res. 16 , 67 (1983 ).
43.
Keil
R. G.
Graham
T. P.
, and
Roenker
K. P.
, Appl. Spectrosc. 30 , 1 (1976 ).
44.
Hipps
K. W.
, J. Electron Spectrosc. Relat. Phenom. 30 , 275 (1983 ).