Raman spectra of three readily available C-type stoichiometric rare-earth sesquioxide powders of composition Ln2O3 are presented. Some correlations of spectra with body-cell structure and infrared absorption spectra have been made. Spectra of Eu2O3, Dy2O3, and Tm2O3 display several new peaks that have not as yet been reported. Assignments of certain peaks to electronic Raman and resonance Raman transitions are discussed.
EyringL., “The Binary Rare Earth Oxides,” in Handbook on the Physics and Chemistry of Rare Earths, GeschneidnerK. A.EyringL., Eds. (North Holland, New York, 1979), Chap. 27, p. 337.
4.
PaulingL.ShappellM. D., Z. Krist.75, 128 (1930).
5.
McDevittN. T.DavidsonA. D., J. of Apt. Soc. Amer.56, 636 (1966).
6.
BloorD.DeanJ. R., J. Phys. C. Solid State Phys.5, 1237 (1972).
ZarembowitchJ.GouteronJ.LejusA. M., J. Raman Spectroscopy9, 263 (1980).
9.
GouteronJ.MichaelD.LejusA. M., Solid State Chem.38, 288 (1981).
10.
FateleyW. G.DollishF. R.McDevittN. T.BentleyF. F., Infrared and Raman Selection Rules for Molecular and Lattice Vibrations: The Correlation Method (Wiley-Interscience, New York, 1972), p. 135.
SchaakG.KoningsteinJ. A., J. Opt. Soc. Amer.60, 1110 (1970).
14.
NieuwpoortW. C.BlasseG.BrilA., “Some Aspects of the Eu3+ Fluorescence in Metaloxide Host Lattices,” in Optical Properties of Ions in Crystals, CrosswhiteH. M.MoosH. W., Eds. (Interscience, New York, 1967), p. 161.
15.
CaroP., Structure Électronique des Éléments de Transition (Presses Universitaires de France, 1976), p. 137.