Abstract
Fourier Transform Infrared Photoacoustic (FT-IR/PA) spectroscopy provides a means to obtain high quality spectra of polyparaphenylene (PPP), an organic semiconductor. Spectra of PPP prepared by two different methods, heavily n-doped PPP, and a new organometallic derivative, PPP(Mo(CO)3)0.25 are presented. Spectral acquisition times for these polymers can be as low as one minute.
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References
1.
Etemad
S.
Heeger
A. J.
, and
MacDiarmid
A. G.
, Ann. Rev. Phys. Chem. 33 , 443 (1982 ).
2.
Su
W. P.
Schrieffer
J. R.
, and
Heeger
A. J.
, Phys. Rev. B 22 , 2099 (1980 ).
3.
Shacklette
L. W.
Chance
R. R.
Ivory
D. M.
Miller
G. G.
, and
Baughman
R. H.
, Synth. Met. 1 , 307 (1980 ).
4.
Tomkiewicz
Y.
Schultz
T. D.
Brom
H. B.
Taranko
A. R.
Clarke
T. C.
, and
Street
G.B.
, Phys. Rev. B 24 , 4348 (1981 ).
5.
Riseman
S. M.
Uaniger
S. I.
Eyring
E. M.
Macinnes
D. A.
MacDiarmid
A. G.
, and
Heeger
A. J.
, Appl. Spectrosc. 35 , 557 (1981 ).
6.
Yaniger
S. I.
Riseman
S. M.
Frigo
T.
, and
Eyring
E. M.
, J. Chem. Phys. 76 , 4298 (1982 ).
7.
Collman
J. P.
and
Hegedus
L. S.
, Principles and Application of Organotransition Metal Chemistry (University Science Books , Mill Valley, CA , 1980 ).
8.
Kovacic
P.
and
Kyriakis
A.
, J. Am. Chem. Soc. 85 , 454 (1963 ).
9.
Yamamoto
T.
and
Yamamoto
A.
, Chem. Lett. 353 (1977 ),
Yamamoto
T.
Hayashi
Y.
, and
Yamamoto
A.
, Bull. Chem. Soc. Jpn. 51 , 2091 (1978 ).
10.
Tate
D. P.
Knipple
W. R.
, and
Augl
J. M.
, Inorg. Chem. 1 , 433 (1962 ).
11.
Riseman
S. M.
and
Eyring
E. M.
, Spectrosc. Lett. 14 , 163 (1981 ).
12.
Yaniger
S.
and
Eyring
E. M.
, unpublished results.
13.
Shacklette
L. W.
Eckhardt
H.
Chance
R. R.
Miller
G. G.
Ivory
D. M.
, and
Baughman
R. H.
, J. Chem. Phys. 73 , 4098 (1980 ).
14.
Froyer
G.
Maurice
F.
Bernier
P.
, and
McAndrew
P.
, Polymer 23 , 1103 (1982 ).
15.
Vidrine
D. W.
, Appl. Spectrosc. 34 , 314 (1980 ).
16.
Kovacic
P.
and
Oziomek
J.
, J. Org. Chem. 29 , 100 (1964 ).
17.
Buttery
H. J.
Keeling
G.
Kettle
S. F.
Paul
I.
, and
Stamper
P. J.
, J. Chem. Soc. A , 2077 (1969 ).
