Abstract
A commercial step-scan FT-IR spectrometer has been used to obtain photoacoustic spectra of carbon black, coals, polymers, and clays. Variation of the external modulation frequency from 40 to 400 Hz shows that saturation affects many of the spectra. Nevertheless, comparison of spectra of oxidized coal with spectra of fresh coal obtained at the corresponding modulation frequencies yields results implying successful depth profiling. Several suggestions for further experiments are also presented.
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References
1.
Palmer
R. A.
Smith
M. J.
Manning
C. J.
Chao
J. L.
Boccara
A. C.
Fournier
D.
, in Photoacoustic and Photothermal Phenomena, Proceedings of the 5th International Topical Meeting ,
Hess
P.
Pelzl
J.
, Eds. (Springer-Verlag , Berlin , 1988 ), p. 50 .
2.
Simon
A.
Seebode
J.
Zachmann
G.
, Paper presented at 6th International Conference on Fourier Transform Spectroscopy (1987); R. Rubinovitz, J. Seebode, and A. Simon, Bruker Report , 35 (1988 ).
3.
Smith
M. J.
Manning
C. J.
Palmer
R. A.
Chao
J. L.
, Appl. Spectrosc. 42 , 546 (1988 ).
4.
Michaelian
K. H.
, Infrared Phys. (in press) .
5.
Richards
P. L.
, J. Opt. Soc. Am. 54 , 1474 (1964 ).
6.
Connes
J.
Connes
P.
, J. Opt. Soc. Am. 56 , 896 (1966 ).
7.
(a)
Debarre
D.
Boccara
A. C.
Fournier
D.
, Appl. Opt. 20 , 4281 (1981 ); (b)
Debarre
D.
Boccara
A. C.
Fournier
D.
, in Photoacoustic Effect: Principles and Applications ,
Leuscher
E.
Ed. (Vieweg , Braunschweig , 1984 ), p. 147 .
8.
(a)
Lloyd
L. B.
Riseman
S. M.
Burnham
R. K.
Eyring
E. M.
Farrow
M. M.
, Rev. Sci. Instr. 51 , 1488 (1980 ); (b)
Lloyd
L. B.
Burnham
R. K.
Chandler
W. L.
Eyring
E. M.
Farrow
M. M.
, Anal. Chem. 52 , 1595 (1980 ).
9.
Donini
J. C.
Michaelian
K. H.
, Infrared Phys. 24 , 157 (1984 ).
10.
Adams
M. J.
Beadle
B.C.
King
A. A.
Kirkbright
G. F.
, Analyst 101 , 553 (1976 ).
11.
Adams
M. J.
Kirkbright
G. F.
, Analyst 102 , 281 (1977 ).
12.
Kirkbright
G. F.
, Optica Pura y Aplicada 11 , 125 (1978 ).
13.
Kato
K.
Ishino
S.
Sugitani
Y.
, Chem. Lett. 783 (1980 ).
14.
O'Hara
E. P.
Tom
R. D.
Moore
T. A.
, Photochem. Photobiol. 38 , 709 (1983 ).
15.
Anjo
D. M.
Moore
T. A.
, Photochem. Photobiol. 39 , 635 (1984 ).
16.
Kirkbright
G. F.
Miller
R. M.
Spillane
D. E. M.
Sugitani
Y.
, Anal. Chem. 56 , 2043 (1984 ).
17.
Uejima
A.
Sugitani
Y.
Nagashima
K.
, Anal. Sci. 1 , 5 (1985 ).
18.
Boucher
F.
Leblanc
R. M.
Savage
S.
Beaulieu
B.
, Appl. Opt. 25 , 515 (1986 ).
19.
Nery
J. W.
Pessoa
O.
Vargas
H.
Reis
F. de A. M.
Gabrielli
A. C.
Miranda
L. C. M.
Vinha
C. A.
, Analyst 112 , 1487 (1987 ).
20.
(a)
Vidrine
D. W.
, Proc. SPIE 289 , 355 (1981 ); (b)
Vidrine
D. W.
, in Fourier Transform Infrared Spectroscopy ,
Ferraro
J. R.
Basile
L. J.
, Eds. (Academic Press , New York , 1982 ), Vol. 3 , pp. 125 –148 ; (c)
Vidrine
D. W.
Lowry
S. R.
, Advances in Chemistry Series (Polym. Charact.) 203 , 595 (1983 ).
21.
Muraishi
S.
, J. Spectrosc. Soc. Japan 33 , 269 (1984 ).
22.
Yang
C. Q.
Ellis
T. J.
Bresee
R. R.
Fateley
W. G.
, Polymeric Materials Science and Engineering 53 , 169 (1985 ).
23.
Teramae
N.
Tanaka
S.
, Appl. Spectrosc. 39 , 797 (1985 ).
24.
Ochiai
S.
, Toso Kogaku 20 , 192 (1985 ).
25.
Urban
M. W.
Koenig
J. L.
, Appl. Spectrosc. 40 , 994 (1986 ).
26.
Zerlia
T.
, Appl. Spectrosc. 40 , 214 (1986 ).
27.
Yang
C. Q.
Bresee
R. R.
Fateley
W. G.
, Appl. Spectrosc. 41 , 889 (1987 ).
28.
Yang
C. Q.
Fateley
W. G.
. Anal. Chim. Acta 194 , 303 (1987 ).
29.
Rosencwaig
A.
, Photoacoustics and Photoacoustic Spectroscopy (Wiley , New York , 1980 ).
30.
McClelland
J. F.
Kniseley
R. J.
, Appl. Phys. Lett. 28 , 467 (1976 ).
31.
Cremers
C. J.
, in Thermal Conductivity 18, Proceedings of the Eighteenth International Thermal Conductivity Conference ,
Ashworth
T.
Smith
D. R.
, Eds. (Plenum Press , New York , 1985 ), pp. 699 –707 .
32.
Michaelian
K. H.
Bukka
K.
Permann
D. N. S.
, Can. J. Chem. 65 , 1420 (1987 ).
