Abstract
A spectroscopic band profile that can be used for asymmetric as well as for symmetric bands is proposed. The meaning of the asymmetry parameter is discussed, and the applications of this profile in infrared intensity determinations are examined.
Get full access to this article
View all access options for this article.
References
1.
Jones
R. N.
and
Sandorfy
C.
, in Chemical Applications of Infrared Spectroscopy ,
West
W.
, Ed. (Wiley , New York , 1956 ), p. 280 .
2.
Seshadri
K. S.
and
Jones
R. N.
, Spectrochim. Acta 19 , 1013 (1963 ).
3.
Young
R. P.
and
Jones
R. N.
, Chem. Rev. 71 , 219 (1971 ).
4.
Fraser
R. D. B.
and
Suzuki
E.
, Anal. Chem. 41 , 37 (1969 ).
5.
Pitha
J.
and
Jones
R. N.
, Can. J. Chem. 45 , 2347 (1967 ).
6.
Cabana
A.
and
Sandorfy
C.
, Spectrochim. Acta 16 , 335 (1960 ).
7.
Gold
H. S.
Rechsteiner
C. E.
, and
Buck
R. P.
, Anal. Chem. 48 , 1540 (1976 ).
8.
Hawranek
J. P.
, Acta Phys. Polon. 40 , 811 (1971 ).
9.
Hawranek
J. P.
Neelakantan
P.
Young
R. P.
, and
Jones
R. N.
, Spectrochim. Acta 32A , 75 (1976 ), 32A , 85 (1976 );
Hawranek
J. P.
and
Jones
R. N.
, Spectrochim. Acta 32A , 99 (1976 ); 32A , 111 (1976 ).
10.
Fraser
R. D. B.
and
Suzuki
E.
, Anal. Chem. 38 , 1770 (1966 ).
11.Program PAAP (Profile Analysis of an Asymmetrical Peak) , available from our laboratory.
12.
Van Haverbeke
L.
and
Desseyn
H. O.
, Ind. Chim. Beige 39 , 142 (1971 ).
13.
Wilson
E. B.
Jr.
and
Wells
A. J.
, J. Chem. Phys. 14 , 578 (1946 ).
14.
Bourgin
D. G.
, Phys. Rev. 29 , 794 (1927 ).
15.
Ramsay
D. A.
, J. Am. Chem. Soc. 74 , 72 (1952 ).
16.
Kabiel
A. M.
and
Tera
F. M.
, Z. Phys. Chem. 234 , 19 (1965 ).
17.
Van Haverbeke
L.
and
Herman
M. A.
, Appl. Spectrosc. 28 , 580 (1974 ).
18.
Van Haverbeke
L.
and
Desseyn
H. O.
, Ind. Chim. Beige 39 , 239 (1974 ).