The technique of inelastic electron tunneling spectroscopy (IETS) is reviewed. The physical principles involved, the theoretical status, and the experimental techniques necessary to obtain tunneling spectra are presented. The details of sample preparation and the necessary measuring circuits are discussed thoroughly. The application of IETS to analytical chemistry and surface interactions is illustrated through a review of the spectra that have been obtained from 1966 to the present.
JaklevicR. C. and LambeJ., Phys. Rev. Lett.17, 1139 (1966).
2.
DukeC. B., Tunneling in Solids, (Academic Press, New York, 1969), p. 279.
3.
GundlachK. H., “Results of Elastic and Inelastic Electron Tunneling Through Potential Barriers in Solids,” in Advances in Solid State Physics, MadelungO. Ed. (Pergamon Press, Oxford and Vieweg, Braunschweig, 1971), pp. 237–271.
4.
McMillanW. L. and RowellJ. M., “Tunneling and Strong-Coupling Superconductivity,” in Superconductivity, ParksR. D., Ed. (Dekker, New York, 1967), Chap. 11.
5.
BursteinE. and LundqvistS., Eds. Tunneling Phenomena in Solids, (Plenum, New York, 1969).
6.
ColemanR. V.MorrisR. C., and ChristopherJ. E., “Experiments on Electron Tunneling in Solids,” in Methods of Experimental Physics, ColemanR. V., Ed. (Academic Press, New York, 1974), Vol. 11, p. 123.
7.
EsakiL., Science183, 1149 (1974).
8.
GiaeverI.Science183, 1253 (1974).
9.
JosephsonB. D., Science184, 527 (1974).
10.
EsakiL., Rev. Mod. Phys.46, 237 (1974).
11.
GiaeverI., Rev. Mod. Phys.46, 245 (1974).
12.
JosephsonB. D., Rev. Mod. Phys.46, 251 (1974).
13.
GundlachK. H. and HolzlJ., Sur. Sci.27, 125 (1971).
14.
BrinkmanW. F.DynesR. C., and RowellJ. M., J. Appl. Phys.41, 1915 (1970).
15.
ScalapinoD. J. and MarcusS. M., Phys. Rev. Lett.18, 459 (1967).
16.
LambeJ. and JaklevicR. C., Phys. Rev.165, 821 (1968).
17.
LambeJ. and JaklevicR. C., “Molecular Excitations in Barriers II,” in Tunneling Phenomena in Solids, BursteinE. and LundqvistS., Eds. (Plenum, New York, 1969), p. 243.
18.
MerzbacherE., Quantum Mechanics, (Wiley, New York, 1961), 2nd ed., pp. 118, 479.
19.
BennettA. J.DukeC. B., and SilversteinS. D., Phys. Rev.176, 969 (1968).
20.
BrailsfordA. D. and DavisL. C.Phys. Rev. B2, 1708 (1970).
21.
DavisL. C., Phys. Rev. B2, 1714 (1970).
22.
SchattkeW. and BirknerG. K., Z. Physik252, 12 (1972).
23.
BirknerG. K. and SchattkeW., Z. Physik256, 185 (1972).
24.
PooleC. P.Jr., Electron Spin Resonance (Interscience, New York, 1967), pp. 387, 775.
25.
O'HaverT. C. and GreenG. L., Amer. Lab.7, 15 (1975).
26.
HoustonJ. E., Rev. Sci. Instr.45, 897 (1974).
27.
PattersonW. R. and ShewchunJ., Rev. Sci. Instr.35, 1704 (1964).
28.
AdlerJ. G. and JacksonJ. E., Rev. Sci. Instr.37, 1049 (1966).
29.
ThomasD. E. and RowellJ. M., Rev. Sci. Instr.36, 1301 (1965).
30.
JenningsR. J. and MerrillJ. R., J. Phys. Chem. Solids33, 1261 (1972).
31.
SimpsonR. E., Introduction to Electronics for Scientists and Engineers, (Allyn and Bacon, Boston, 1974), p. 394.
32.
DiefenderferA. J., Principles of Electronic Instrumentation, (Saunders, Co., Philadelphia, 1972), p. 477.
33.
BrannerG. R.FriarE. M., and MedicusG.Rev. Sci. Instr.34, 231 (1963).
34.
HebardA. F. and ShumateP. W., Rev. Sci. Instr.45, 529 (1974).
35.
KleinJ.LegerA.BelinM.DefourneauD., and SangsterM. J. L., Phys. Rev. B.7, 2336 (1973).
36.
SimonsenM. G.ColemanR. V., and HansmaP. K., J. Chem. Phys.61, 3789 (1974).
37.
LittleL. H., Infrared Spectra of Absorbed Species, (Academic Press, New York, 1966), Chap. 15.
38.
SchriefferJ. R., “Single Particle Tunneling in Superconductors,” in Tunneling Phenomena in Solids, BursteinE. and LundqvistS., Eds. (Plenum, New York, 1966), p. 287.
39.
BardeenJ., Phys. Rev. Lett.6, 57 (1961).
40.
GiaeverI.HartH. R., and MegerleK., Phys. Rev.126, 941 (1962).
41.
ShewchunJ. and WaxmanA., Rev. Sci. Instr.37, 1195 (1966).
42.
RogersJ. S., Rev. Sci. Instr.41, 1184 (1970).
43.
BlackfordB. L., Rev. Sci. Instr.42, 1198 (1971).
44.
AdlerJ. G.ChenT. T., and StrausJ., Rev. Sci. Instr.42, 362 (1971).
45.
AltweinM. and FinkenrathH., J. Phys. E6, 770 (1973).
46.
LewisB. F.MosesmanM., and WeinbergW. H., Surf. Sci.41, 142 (1974).
47.
AdlerJ. G. and StrausJ., Rev. Sci. Instr.46, 158 (1975).
48.
LarsonD. C., “Experimental Methods in the Preparation and Measurement of Thin Films,” in Methods of Experimental Physics, ColemanR. V., Ed. (Academic Press, New York, 1974), Vol. 11, p. 619.
49.
MilesJ. and SmithP., J. Electrochem. Soc.110, 1240 (1963).
50.
HansmaP. K. and ColemanR. V., Science184, 1369 (1974).
51.
RoenkerK. P.GrahamT. P., and KeilR. G., submitted to Surf. Sci.
ChenT. T. and AdlerJ. G., Solid State Commun.8, 1965 (1970).
61.
AdlerJ. G., Phys. Lett.29 A, 675 (1969).
62.
AdlerJ. G., Solid State Commun.7, 1635 (1969).
63.
RowellJ. M.McMillanW. L., and FeldmannW. L., Phys. Rev.180, 658 (1969).
64.
YansonI. K., Soviet Phys. JETP33, 951 (1971).
65.
RochlinG. I. and HansmaP. K., Phys. Rev.B 2, 1460 (1970).
66.
ChubovP. N. and YansonI. K., Soviet Phys. Solid State15, 2484 (1974).
67.
GeigerA. L.ChandrasekharB. S., and AdlerJ. G., Phys. Rev.188, 1130 (1969).
68.
HandyR. M.Phys. Rev.126, 1968 (1962).
69.
YansonI. K.BogatinaN. I.VerkinB. I., and ShklyarevskiiO. I., Soviet Phys. JETP35, 540 (1972).
70.
GiaeverI. and ZellerH. R., Phys. Rev. Lett.21, 1385 (1968).
71.
YansonI. K. and BogatinaN. I., Soviet Phys. JETP32, 823 (1971).
72.
JaklevicR. C. and LambeJ., Phys. Rev. B2, 808 (1970).
73.
ShklyarevskiiO. I.YansonI. K., and ZaporonzhskiiV. D., Solid State Commun.14, 327 (1974).
74.
LegerA.KleinJ.BelinM., and DefourneauD., Solid State Commun.11, 1331 (1972).
75.
KleinJ. and LegerA., Phys. Lett.30 A, 96 (1969).
76.
JaklevicR. C.LambeJ.MikkorM., and VassellW. C., Phys. Rev. Lett.26, 88 (1971).
77.
JaklevicR. C.LambeJ.MikkorM., and VassellW. C., Solid State Comm.10, 199 (1972).
78.
JaklevicR. C. and LambeJ., Surf. Sci.37, 922 (1973).
79.
TaylorD. R. and LudlumK. H., J. Phys. Chem.76, 2882 (1972).
80.
SimonsenM. G. and ColemanR. V., Phys. Rev. B8, 5875 (1973).
81.
LewisB. F.BowserW. M.HornJ. L.Jr.LuuT., and WeinbergW. H., J. Vac. Sci. Technol.11, 262 (1974).
82.
WeinbergW. H.BowserW. M., and LewisB. F., Proceedings of the Second International Conference on Solid Surfaces, 1974, Japan, J. Appl. Phys.Suppl.2, Pt. 2, 863 (1974).
83.
SkarlatosY.BarkerR. C.HallerG. L., and YelonA., Surf. Sci.43, 353 (1974).
84.
WalmsleyD. G.McMorrisI. W. N., and BrownN. M. D., Solid State Comm.16, 663 (1975).
85.
VedderW. and VermilyeaD. A., Trans. Faraday Soc.65, 561 (1969).
86.
TakamuraT.Kihara-MorishitaH., and MoriyamaV., Thin Solid Films, 6, R17 (1970).