Abstract
Recent advances in NMR spectroscopy allow one to study extremely dilute systems or nuclei which occur in low natural abundance and/or have poor sensitivity for NMR detection. This paper describes various pulse and pulse Fourier transform NMR techniques. Included in this introduction are: (1) a brief review of the nuclear relaxation phenomenon, (2) sensitivity enhancement using the pulse technique, (3) pulse instrumentation, and (4) the analytical applications of pulse Fourier transform NMR.
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References
1.
Emsley
J. W.
Feeney
J.
Sutcliffe
L. H.
, High Resolution Nuclear Magnetic Resonance Spectroscopy (Pergamon Press , New York , 1965 ), Vol. 1 , p. 50 .
2.
Pople
J. A.
Schneider
W. G.
Bernstein
H. J.
, High Resolution Nuclear Magnetic Resonance (McGraw-Hill , New York , 1959 ), p. 43 .
3.
Waugh
J. S.
, (Ed.), Advances in Magnetic Resonance (Academic Press , New York , 1966 ), Vol. 2 , p. 1 .
4.
Farrar
T. C.
Becker
E. D.
, Pulse and Fourier Transform NMR (Academic Press , New York , 1971 ).
5.
Becker
E. D.
, High Resolution NMR (Academic Press , New York , 1969 ).
6.
Ernst
R. R.
Anderson
W. A.
, Rev. Sci. Instr. 37 , 93 (1966 ).
7.
Torrey
H. C.
, Phys. Rev. 76 , 1059 (1949 ).
8.
Hahn
E. L.
, Phys. Rev. 80 , 580 (1950 ).
9.
Carr
H. Y.
Purcell
E. M.
, Phys. Rev. 94 , 630 (1954 ).
10.
Meiboom
S.
Gill
D.
, Rev. Sci. Instr. 29 , 688 (1958 ).
11.Technical Information Bulletin R-2 Nuclear Magnetic Resonance Specialities, Inc. , New Kensington, Pa. 15068.
12.“Pulsed NMR Spectrometers” and “Digital Pulse Program Generator,” Bruker Scientific Inc. , Westchester Ind., Park Elmsford, New York .
13.
Lowe
I. J.
Norberg
R. E.
, Phys. Rev. 107 , 46 (1957 ).
14.
Becker
E. D.
Ferretti
J. A.
Farrar
T. C.
, J. Am. Chem. Soc. 91 , 7784 (1969 ).
15.
Allerhand
A.
Cochran
D. W.
, J. Am. Chem. Soc. 92 4482 (1970 ).
16.
Void
R. L.
Chan
S. O.
, J. Mag. Resonance 4 , 208 (1971 ).
17.
Cooley
J. W.
Tukey
J. W.
, Math. Comput. 19 , 297 (1965 ).
18.
Reich
H. J.
Jautelat
M.
Messe
M. T.
Weigert
F. J.
Roberts
J. D.
, J. Am. Chem. Soc. 91 , 7445 (1969 ).
19.
Horsley
W.
Sternlicht
H.
Cohen
J. S.
, J. Am. Chem. Soc. 92 , 680 (1970 ).
20.
Allerhand
A.
Cochran
D. W.
Doddrell
D.
, Proc. Nat. Acad. Sci. U. S. 67 , 1093 (1970 ).
21.
Lanterbur
P. C.
, Appl. Spectrosc , 24 , 450 (1970 ).
22.
Schaefer
J.
, Macromolecules 4 , 98 , 105 , 107 , 110 (1971 ).
23.
Reich
H. J.
Jautelat
M.
Messe
M. T.
Weigert
F. J.
Roberts
J. D.
, J. Am. Chem. Soc. 91 , 7445 (1969 ).
24.
Gansow
O. A.
Schittenhelm
W.
, J. Am. Chem. Soc. 93 , 4294 (1971 ).
25.
Void
R. L.
Waugh
J. S.
Klein
M. P.
Phelps
D. E.
, J. Chem. Phys. 48 , 3831 (1968 ).
26.
Freeman
R.
Hill
H. D. W.
, J. Chem. Phys. 51 , 3140 (1969 ).
27.
Freeman
R.
Hill
H. D. W.
, J. Chem. Phys. 53 , 4103 (1970 ).
28.
Doddrell
D.
Allerhand
A.
, J. Am. Chem. Soc. 93 , 1558 (1971 ).
29.
Allerhand
A.
Doddrell
D.
, J. Am. Chem. Soc. 93 , 2777 (1971 ).
30.
Doddrell
D.
Allerhand
A.
, J. Am. Chem. Soc. 93 , 2779 (1971 ).
31.
Freeman
R.
Hill
H. D. W.
, J. Mag. Resonance 4 , 366 (1971 ).
