The mineralogy and its geological origin of the Late Permian No. 6 coal seam from the Qinglong Coalfield, western Guizhou Province, were determined by the methods of powder X-ray diffraction (XRD) and scanning electron microscopy equipped with energy-dispersive X-ray spectrometer (SEM-EDX). A particular material consists of volcanic ash, detrital materials of terrigenous origin, and organic matter in this coal seam was determined. The results confirmed that the volcanic-derived material exactly exists in coal. Four structure types of the volcanic-derived materials were classified according to their shapes and occurrence modes. It is the first time that the authors found a relative high content of bornite in coal, which was attributed to the basic volcanic ash.
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