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Abstract

Fungal cellulases have been shown to be less efficient in modified wood than in untreated wood (Lekounogou et al. 2008; Venås 2008). However, Verma and Mai (2010) showed that cellulase efficacy is partly restored in 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) treated wood by pre-treatment with Fenton's reagent, simulating the oxidative degradation phase in initial brown rot decay. In this study, we examined whether Fenton derived hydroxyl radicals (·OH) and cellulases are able to cleave polysaccharides in furfurylated and acetylated wood and to what extent enzyme efficacy is increased by oxidative pre-treatment of these materials. The results show that fungal cellulases were able to degrade acetylated wood and that the cellulase efficacy was increased by oxidative pre-treatment by 20%, which is half of the increase in untreated wood. Furthermore, the results indicate that poly(furfuryl alcohol) is degraded by Fenton derived ·OH. This indicates a possible route for the eventual degradation of modified wood.

Keywords

Acetylated wood Chelator mediated Fenton (CMF) degradation Fenton's reagent Furfurylated wood Mode of action

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In vitro oxidative and enzymatic degradation of modified wood

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