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Abstract

²⁷Al and ²⁹Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) and powder X-ray diffraction (XRD) studies of Portland type cement clinkers are reported. Common phases in such cements (C₂S, C₃S, C₃A and C₄AF) were prepared with high purity grade chemical reagents to be used as reference, and characterised. Subsequently, clinkers with selected compositions were prepared by combining several industrial wastes and byproducts: Al rich anodising sludge, sludge from the filtration/clarification of potable water, sludge generated in marble sawing processes and foundry sand. The clinkers were found to contain the reference cementitious phases, the two characterisation techniques used (NMR and XRD) being complementary in the information provided. The general similarity of the major phases formed in waste based and reagent based formulations clearly demonstrates the potential of the use of wastes in cement formulations of industrial interest.

Keywords

CLINKER NMR XRD WASTES

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References

Dondi

, Marsigli

and Fabbri

: Tile Brick Int., 1997, 13, 302–308.

Canpolat

, Ylmaz

, Köse

M. M.

, Stimer

and Yurdusev

M. A.

: Cement Concrete Res., To be published.

Tulyaganov

D. U.

, Olhero

S. M. H.

, Ribeiro

M. J.

, Ferreira

J. M. F.

and Labrincha

J. A.

: J. Mater. Synt. Proc., 2002, 10, 311–318.

Pereira

D. A.

, Couto

D. M.

and Labrincha

J. A.

: Ceramic Forum Int., 2000, 77, 21–25.

Martelon

, Jarrige

, Ribeiro

M. J.

, Ferreira

J. M. F.

, and Labrincha

J. A.

: Ind. Ceramic., 2000, 20, 71–76.

Couto

D. M.

, Ringuedé

, Silva

R. F.

, Labrincha

J. A.

and Rodrigues

C. M. S.

: Am. Ceram. Bull., 2003, 82, 9101–9103.

Pereira

D. A.

, Aguiar

J. B.

, Castro

F. P.

, Almeida

M. F.

and Labrincha

J. A.

: Cement Concrete Res., 2000, 30, 1131–1138.

Pinto

, Rosenbom

, Machado

, Labrincha

J. A.

and Ferreira

V. M.

: Key Eng. Mater., 2004, 264–2268, 1391–1394.

Maruta

, Ohmori

, Moriya

, Uchida

and Isoda

: Inorganic Mater., 1997, 4, 152–155.

10.

Gluchowski

W. D.

, Zajtsew

and Pachomow

: Silicate Indust., 1983, 48, 197–200.

11.

Taylor

H. F. W.

: ‘The chemistry of cement’, 1st edn; 1964, London, Academic Press.

12.

Lea

F. M.

: ‘The chemistry of cement and concrete’, 4th edn; 2001, New York, Chemical Publishing Co.

13.

Hong

, Fu

and Min

: Cement Concrete Res., 2001, 31, 287–290.

14.

Maki

, Fukuda

, Imura

, Yoshida

and Ito

: Cement Concrete Res., 1995, 25, 835–840.

15.

Stanek

and Sulovsky

: Cement Concrete Res., 2002, 32, 1169–1175.

16.

Gobbo

, Sant'Agostino

and Garcez

: Cement Concrete Res., 2004, 34, 657–664.

17.

Stephan

, Mallmann

, Knöfel

and Härdtl

: Cement Concrete Res., 1999, 29, 1949–1957.

18.

Schneider

, Cincotto

M. A.

and Panepucci

: Cement Concrete Res., 2001, 31, 993–100.

19.

Andersen

M. D.

, Jakobsen

H. J.

and Skibsted

: Cement Concrete Res., 2004, 34, 857–868.

20.

Engelhardt

and Michel

: ‘High-resolution solid-state NMR of silicates and zeolites’; 1987, New York, John Wiley & Sons.

21.

Raupp-Pereira

, Nunes

A. F.

, Segaddes

A. M.

and Labrincha

J. A.

: Key Eng. Mater., 2004, 264–268, 1743–1747.

22.

Raupp-Pereira

, Hotza

, Segadães

A. M.

and Labrincha

J. A.

: Ceramics Int., 2006, 32, 173–179.

23.

Raupp-Pereira

, Hotza

, Segadães

A. M.

and Labrincha

J. A.

: Proc. UNITECR'03, Osaka, Japan, 2003, TARJ, 150–153.

27 Al and 29 Si NMR and XRD characterisation of clinkers: Standard phases and new waste based formulations

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